Answer:
A) 8.51 × 10²⁴
Explanation:
1. Gather all the information
2H₂S + SO₂ ⟶ 3S + 2H₂O
n/mol: 9.42
2. Calculate the moles of S atoms
The molar ratio is 3 mol S:2 mol H₂S
3. Calculate the atoms of S
The one that is being described above is what we call SCIENTIFIC LAW. Scientific law is what explains of what will happen every time in a certain situation. This is also different from scientific theory since scientific theory only gives an explanation to a group of happenings and this can still be modified. Hope this helps.
0.040 mol / dm³. (2 sig. fig.)
<h3>Explanation</h3>
in this question acts as a weak base. As seen in the equation in the question, produces 
rather than 
when it dissolves in water. The concentration of will likely be more useful than that of for the calculations here.
Finding the value of ![[\text{OH}^{-}]](https://tex.z-dn.net/?f=%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D)
from pH:
Assume that 
,
.
![[\text{OH}^{-}] =10^{-\text{pOH}} =10^{-2.80} = 1.59\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D%20%3D10%5E%7B-%5Ctext%7BpOH%7D%7D%20%3D10%5E%7B-2.80%7D%20%3D%201.59%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
Solve for ![[(\text{CH}_3)_3\text{N}]_\text{initial}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D)
:
![\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Bequilibrium%7D%7D%20%3D%20%5Ctext%7BK%7D_b%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D)
Note that water isn't part of this expression.
The value of Kb is quite small. The change in is nearly negligible once it dissolves. In other words,
![[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D%20%3D%20%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Bfinal%7D)
.
Also, for each mole of produced, one mole of 
was also produced. The solution started with a small amount of either species. As a result,
![[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D%20%3D%20%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D%20%3D%2010%5E%7B-2.80%7D%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
![\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctextbf%7Binitial%7D%7D%20%3D%20%5Ctext%7BK%7D_b%20%3D%201.58%5Ctimes%2010%5E%7B-3%7D)
,
![[(\text{CH}_3)_3\text{N}]_\textbf{initial} =\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{\text{K}_b}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctextbf%7Binitial%7D%20%3D%5Cdfrac%7B%5B%5Ctext%7BOH%7D%5E%7B-%7D%5D_%5Ctext%7Bequilibrium%7D%5Ccdot%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BNH%7D%5E%7B%2B%7D%5D_%5Ctext%7Bequilibrium%7D%7D%7B%5Ctext%7BK%7D_b%7D)
,
![[(\text{CH}_3)_3\text{N}]_\text{initial} =\dfrac{(1.58\times10^{-3})^{2}}{6.3\times10^{-5}} = 0.040\;\text{mol}\cdot\text{dm}^{-3}](https://tex.z-dn.net/?f=%5B%28%5Ctext%7BCH%7D_3%29_3%5Ctext%7BN%7D%5D_%5Ctext%7Binitial%7D%20%3D%5Cdfrac%7B%281.58%5Ctimes10%5E%7B-3%7D%29%5E%7B2%7D%7D%7B6.3%5Ctimes10%5E%7B-5%7D%7D%20%3D%200.040%5C%3B%5Ctext%7Bmol%7D%5Ccdot%5Ctext%7Bdm%7D%5E%7B-3%7D)
.
Cobalt because it has an atomic mass of 58 and 33 neutrons.
