The scheme is shown below, the steps involved are as follow,
Step one: Reduction: The carbonyl group of given compound on reduction using
Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation: The double bond present in starting compound when treated with
m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction: The epoxide is reduced to alcohol on treatment with
Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation: The hydroxyl group (alcohol) is
oxidized to carbonyl (ketonic group) using oxidizing agent
Chromic acid (H</span>₂CrO₄).
Answer:
3. 3.45×10¯¹⁸ J.
4. 1.25×10¹⁵ Hz.
Explanation:
3. Determination of the energy of the photon.
Frequency (v) = 5.2×10¹⁵ Hz
Planck's constant (h) = 6.626×10¯³⁴ Js
Energy (E) =?
The energy of the photon can be obtained by using the following formula:
E = hv
E = 6.626×10¯³⁴ × 5.2×10¹⁵
E = 3.45×10¯¹⁸ J
Thus, the energy of the photon is 3.45×10¯¹⁸ J
4. Determination of the frequency of the radiation.
Wavelength (λ) = 2.4×10¯⁵ cm
Velocity (c) = 3×10⁸ m/s
Frequency (v) =?
Next, we shall convert 2.4×10¯⁵ cm to metre (m). This can be obtained as follow:
100 cm = 1 m
Therefore,
2.4×10¯⁵ cm = 2.4×10¯⁵ cm × 1 m /100 cm
2.4×10¯⁵ cm = 2.4×10¯⁷ m
Thus, 2.4×10¯⁵ cm is equivalent to 2.4×10¯⁷ m
Finally, we shall determine the frequency of the radiation by using the following formula as illustrated below:
Wavelength (λ) = 2.4×10¯⁷ m
Velocity (c) = 3×10⁸ m/s
Frequency (v) =?
v = c / λ
v = 3×10⁸ / 2.4×10¯⁷
v = 1.25×10¹⁵ Hz
Thus, the frequency of the radiation is 1.25×10¹⁵ Hz.
The rate of disappearance of chlorine gas : 0.2 mol/dm³
<h3>Further explanation</h3>
The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time.
For reaction :
The rate reaction :
![\tt -\dfrac{1}{a}\dfrac{d[-A]}{dt}= -\dfrac{1}{b}\dfrac{d[-B]}{dt}=\dfrac{1}{c}\dfrac{d[C]}{dt}=\dfrac{1}{d}\dfrac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctt%20-%5Cdfrac%7B1%7D%7Ba%7D%5Cdfrac%7Bd%5B-A%5D%7D%7Bdt%7D%3D%20-%5Cdfrac%7B1%7D%7Bb%7D%5Cdfrac%7Bd%5B-B%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bc%7D%5Cdfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bd%7D%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D)
Reaction for formation CCl₄ :
<em>CH₄+4Cl₂⇒CCl₄+4HCl</em>
<em />
From equation, rate of reaction = rate of formation CCl₄ = 0.05 mol/dm³
Rate of formation of CCl₄ = reaction rate x coefficient of CCCl₄
0.05 mol/dm³ = reaction rate x 1⇒reaction rate = 0.05 mol/dm³
The rate of disappearance of chlorine gas (Cl₂) :
Rate of disappearance of Cl₂ = reaction rate x coefficient of Cl₂
Rate of disappearance of Cl₂ = 0.05 x 4 = 0.2 mol/dm³
Explanation:
As the water vapor touches the mirror the particles of the vapor loses energy and they move less then the process Condensation takes place in which the gas turns into water.
