Answer:
pH = 2.69
Explanation:
The complete question is:<em> An analytical chemist is titrating 182.2 mL of a 1.200 M solution of nitrous acid (HNO2) with a solution of 0.8400 M KOH. The pKa of nitrous acid is 3.35. Calculate the pH of the acid solution after the chemist has added 46.44 mL of the KOH solution to it.</em>
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The reaction of HNO₂ with KOH is:
HNO₂ + KOH → NO₂⁻ + H₂O + K⁺
Moles of HNO₂ and KOH that react are:
HNO₂ = 0.1822L × (1.200mol / L) = <em>0.21864 moles HNO₂</em>
KOH = 0.04644L × (0.8400mol / L) = <em>0.0390 moles KOH</em>
That means after the reaction, moles of HNO₂ and NO₂⁻ after the reaction are:
NO₂⁻ = 0.03900 moles KOH = moles NO₂⁻
HNO₂ = 0.21864 moles HNO₂ - 0.03900 moles = 0.17964 moles HNO₂
It is possible to find the pH of this buffer (<em>Mixture of a weak acid, HNO₂ with the conjugate base, NO₂⁻), </em>using H-H equation for this system:
pH = pKa + log₁₀ [NO₂⁻] / [HNO₂]
pH = 3.35 + log₁₀ [0.03900mol] / [0.17964mol]
<h3>pH = 2.69</h3>
Answer:
[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.
Explanation:
Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.
Analysis:
H₂CO₃(aq) ⇄ H⁺(aq) + HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷
C(i) 0.115M 0 0
ΔC -x +x +x
C(eq) 0.115M - x x x
≅ 0.115M
Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M
= 4.3 x 10⁻⁷ => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.
In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion concentration, the hydroxide ion concentration is then calculated from
[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.
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NOTE: The 2.32 x 10⁻⁴M value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.
Answer:
i think the answer is C
Explanation:
not sure plsss dont bash im a beginner
Factors that determine ionization energy:
- Electronic Repulsion - If the electronic density decreases, the ionization energy with increase and vice versa. If an electron gets released, it decreases the electronic repulsion. This makes releasing another electron harder than the first on unless the electron that is being released comes from another energetic level.
- # Of Energy Levels - The more energy cores that get filled up, the more ionization levels decrease. When we see the energy levels go from top to bottom, the ionization also go from most to least. This is why ionization occurs on the highest level.
- Nuclear Charge - The higher the atomic number, the higher charge in the nuclei. This also makes the ionization energy higher as it increases from left to right of in other words, if the nuclear charge gets higer, the energy gets higher as well.
Factors that determine atomic volume:
- How many protons are in the nucleus (nuclear charge)
- How many energy levels carry electrons (electrons in outer energy level)
Best of Luck!
Answer:
6.46 × 10⁻¹¹ M
Explanation:
Step 1: Given data
pH of the solution: 3.81
Step 2: Calculate the pOH of the solution
We will use the following expression.
pH + pOH = 14.00
pOH = 14.00 - pH = 14.00 - 3.81 = 10.19
Step 3: Calculate the concentration of OH⁻ ions
We will use the definition of pOH.
pOH = -log [OH⁻]
[OH⁻] = antilog -pOH = antilog -10.19 = 6.46 × 10⁻¹¹ M
