I think the answer would be d but not 100% sure
Answer:
Use a ratio of 0.44 mol lactate to 1 mol of lactic acid
Explanation:
John could prepare a lactate buffer.
He can use the Henderson-Hasselbalch equation to find the acid/base ratio for the buffer.
![\text{pH} = \text{pK}_{\text{a}} + \log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}}\\\\3.5 = 3.86 + \log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}}\\\\\log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}} = 3.5 - 3.86 = -0.36\\\\\dfrac{\text{[A$^{-}$]}}{\text{[HA]}} = 10^{-0.36} = \mathbf{0.44}](https://tex.z-dn.net/?f=%5Ctext%7BpH%7D%20%3D%20%5Ctext%7BpK%7D_%7B%5Ctext%7Ba%7D%7D%20%2B%20%5Clog%5Cdfrac%7B%5Ctext%7B%5BA%24%5E%7B-%7D%24%5D%7D%7D%7B%5Ctext%7B%5BHA%5D%7D%7D%5C%5C%5C%5C3.5%20%3D%203.86%20%2B%20%5Clog%5Cdfrac%7B%5Ctext%7B%5BA%24%5E%7B-%7D%24%5D%7D%7D%7B%5Ctext%7B%5BHA%5D%7D%7D%5C%5C%5C%5C%5Clog%5Cdfrac%7B%5Ctext%7B%5BA%24%5E%7B-%7D%24%5D%7D%7D%7B%5Ctext%7B%5BHA%5D%7D%7D%20%3D%203.5%20-%203.86%20%3D%20-0.36%5C%5C%5C%5C%5Cdfrac%7B%5Ctext%7B%5BA%24%5E%7B-%7D%24%5D%7D%7D%7B%5Ctext%7B%5BHA%5D%7D%7D%20%3D%2010%5E%7B-0.36%7D%20%3D%20%5Cmathbf%7B0.44%7D)
He should use a ratio of 0.44 mol lactate to 1 mol of lactic acid.
For example, he could mix equal volumes of 0.044 mol·L⁻¹ lactate and 0.1 mol·L⁻¹ lactic acid.
Excess reactant : Na
NaCl produced : = 16.497 g
<h3>Further explanation</h3>
Given
Reaction(balanced)
2Na + Cl₂⇒ 2NaCl
20 g Na
10 g Cl₂
Required
Excess reactant
NaCl produced
Solution
mol Na(Ar = 23 g/mol) :
= 20 : 23 = 0.87
mol Cl₂(MW=71 g/mol):
= 10 : 71 g/mol = 0.141
mol : coefficient :
Na = 0.87 : 2 = 0.435
Cl₂ = 0.141 : 1 = 0.141
Limiting reactant : Cl₂(smaller ratio)
Excess reactant : Na
Mol NaCl based on mol Cl₂, so mol NaCl :
= 2/1 x mol Cl₂
= 2/1 x 0.141
= 0.282
Mass NaCl :
= 0.282 x 58.5 g/mol
= 16.497 g