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The product of reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is ethyl 4- hydroxybutanoate .
Sodium borohydride is a relatively selective reducing agent Ethanolic solutions of Sodium borohydride reduces aldehyde , and ketone , in the presence of acid chloride , ester , epoxide , lactones , acids , nitriles , nitro groups.
The sodium borohydride does not reduce ester group because sodium borohydride is not strong enough and the electrophilicity at carbony carbon of ester is not more as compare toaldehyde , and ketone
The product of reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is ethyl 4- hydroxybutanoate .
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Answer:
The correct answer is 146 g/mol
Explanation:
<em>Freezing point depression</em> is a colligative property related to the number of particles of solute dissolved in a solvent. It is given by:
ΔTf = Kf x m
Where ΔTf is the freezing point depression (in ºC), Kf is a constant for the solvent and m is the molality of solution. From the problem, we know the following data:
ΔTf = 1.02ºC
Kf = 5.12ºC/m
From this, we can calculate the molality:
m = ΔTf/Kf = 1.02ºC/(5.12ºC/m)= 0.199 m
The molality of a solution is defined as the moles of solute per kg of solvent. Thus, we can multiply the molality by the mass of solvent in kg (250 g= 0.25 kg) to obtain the moles of solute:
0.199 mol/kg benzene x 0.25 kg = 0.0498 moles solute
There are 0.0498 moles of solute dissolved in the solution. To calculate the molar mass of the solute, we divide the mass (7.27 g) into the moles:
molar mass = mass/mol = 7.27 g/(0.0498 mol) = 145.9 g/mol ≅ 146 g/mol
<em>Therefore, the molar mass of the compound is 146 g/mol </em>
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On earth however, it's much bigger. Our own atmosphere acts similarly to this; it allows heat in, but doesn't allow it to leave which heats up the planet and causes global warming.
