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Answer:
Pressure = 1.14 atm
Explanation:
Hello,
This question requires us to calculate the final pressure of the bottle after thermal equilibrium.
This is a direct application of pressure law which states that in a fixed mass of gas, the pressure of a given gas is directly proportional to its temperature, provided that volume remains constant.
Mathematically, what this implies is
P = kT k = P / T
P1 / T1 = P2 / T2 = P3 / T3 =........= Pn / Tn
P1 / T1 = P2 / T2
P1 = 1.0atm
T1 = -15°C = (-15 + 273.15)K = 258.15K
P2 = ?
T2 = 21.5°C = (21.5 + 273.15)K = 294.65K
P1 / T1 = P2 / T2
P2 = (P1 × T2) / T1
P2 = (1.0 × 294.65) / 258.15
P2 = 1.14atm
The pressure of the gas after attaining equilibrium is 1.14atm
Answer:
Cu(NO3)2(aq)+Pb(s) ⇌ Pb(NO3)2(aq)+Cu(s)
Explanation:
If we look at the both reactions closely, we will quickly discover that the reaction CuSO4(aq)+Pb(s) ⇌ PbSO4(s)+Cu(s) involves PbSO4.
The compound PbSO4 is insoluble in water and sinks to the bottom of the reaction vessel. When this occurs, the concentration of Pb^2+ becomes low. This will bring about a low voltage in the cell.
On the other hand, Pb(NO3)2 is soluble in water hence the cell voltage in this case is higher than the former.
Explanation:
Lithium diisopropylamide (LDA) is used in many organic synthesis and is a strong base. It is prepared by the acid base reaction of N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) and butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ).
The equation is show below as:
[(CH₃)₂CH]₂NH + Li⁺⁻CH₂CH₂CH₂CH₃ ⇒ [(CH₃)₂CH]₂N⁻Li⁺ + CH₃CH₂CH₂CH₃
N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) is a weaker acid and hence, LDA ( [(CH₃)₂CH]₂N⁻Li⁺ ) is stronger base. (Weaker acid has stronger conjugate base)
Butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ) is a very strong base and hence, butane ( CH₃CH₂CH₂CH₃ ) is a very weak acid. (Strong base has weaker conjugate acid)
