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Free_Kalibri [48]
3 years ago
7

1) The heat of combustion for the gases hydrogen, methane and ethane are −285.8, −890.4 and −1559.9 kJ/mol respectively at 298K.

Chemistry
1 answer:
Morgarella [4.7K]3 years ago
3 0

Answer:

The enthalpy of the reaction is 64.9 kJ/mol.

Explanation:

H_2 + \frac{1}{2}O_2\rightarrow H_2O,\Delta H_1 =-285.8 kJ..[1]

CH_4 + 2O_2\rightarrow CO_2 + 2H_2O,\Delta H_2 =-890.4 kJ..[2]

C_2H_6 + \frac{7}{2}O_2\rightarrow 2CO_2 + 3H_2O,\Delta H_3= -1559.9 kJ..[3]

2CH_4(g)\rightarrow C_2H_6(g) + H_2(g),\Delta H_4=?..[4]

2 × [2] - [1]- [3] = [4]  (Using Hess's law)

\Delta H_4=2\times \Delta H_2 -\Delta H_1 -\Delta H_3

\Delta H_4=2\times (-890.4 kJ)-(-285.8 kJ) -(-1559.9 kJ)

\Delta H_4=64.9 kJ/mol

The enthalpy of the reaction is 64.9 kJ/mol.

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The answer for the following problem is mentioned below.

  • <u><em>Therefore the final temperature of the gas is 740 K</em></u>

Explanation:

Given:

Initial pressure of the gas (P_{1}) = 1.8 atm

Final pressure of the gas (P_{2})  = 4 atm

Initial temperature of the gas (T_{1}) = 60°C = 60 + 273 = 333 K

To solve:

Final temperature of the gas (T_{2})

We know;

From the ideal gas equation;

we know;

P  × V = n × R × T

So;

we can tell from the above equation;

 <u>   P ∝ T</u>

(i.e.)

      <em> </em>\frac{P}{T}<em> = constant</em>

        \frac{P_{1} }{P_{2} } = \frac{T_{1} }{T_{2} }

Where;

P_{1}  = initial pressure of a gas

P_{2} = final pressure of a gas

T_{1} = initial temperature of a gas

T_{2} = final temperature of a gas

        \frac{1.8}{4} = \frac{333}{T_{2} }

   T_{2} =\frac{333*4}{1.8}

    T_{2} = 740 K

<u><em>Therefore the final temperature of the gas is 740 K</em></u>

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3 years ago
What is the molarity of a solution prepared by diluting 250 mL of a 40% H2SO4 solution to 1 Liter? The density of the stock solu
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Answer:

1.195 M.

Explanation:

  • We can calculate the concentration of the stock solution using the relation:

<em>M = (10Pd)/(molar mass).</em>

Where, M is the molarity of H₂SO₄.

P is the percent of H₂SO₄ (P = 40%).

d is the density of H₂SO₄ (d = 1.17 g/mL).

molar mass of H₂SO₄ = 98 g/mol.

∴ M of stock H₂SO₄ = (10Pd)/(molar mass) = (10)(40%)(1.17 g/mL) / (98 g/mol) = 4.78 M.

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<em>∴ (MV) before dilution = (MV) after dilution</em>

M before dilution = 4.78 M, V before dilution = 250 mL.

M after dilution = ??? M, V after dilution = 1.0 L = 1000 mL.

∴ M after dilution = (MV) before dilution/(V after dilution) = (4.78 M)(250 mL)/(1000 mL) = 1.195 M.

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