Answer:
A
Explanation:
To answer this, we need to use Gay-Lussac's law, which states that:
, where P is pressure and T is temperature
The initial pressure we're given is 4.5 atm (so P1 = 4.5) and the temperature is 45.0°C; however, we need to change Celsius to Kelvins, so add 273 to 45.0: 45.0 + 273 = 318 K (so T1 = 318).
The final pressure is what we want to find, but we do know the final temperature is 3.1°C. Converting this to Kelvins, we get: 3.1 + 273 = 276.1 K, which means T2 = 276.1.
Plug these values in:

Multiply both sides by 276.1:
≈ 3.9 atm
The answer is thus A.
C. Fixing a wineglass requires a large decrease in entropy.
Answer:
Gas
Increase the pressure
Explanation:
Let's refer to the attached phase diagram for CO₂ (not to scale).
<em>At -57 °C and 1 atm, carbon dioxide is in which phase?</em>
If we look at the intersection between -57°C and 1 atm, we can see that CO₂ is in the gas phase.
<em>At 10°C and 2 atm carbon dioxide is in the gas phase. From these conditions, how could the gaseous CO₂ be converted into liquid CO₂?</em>
Since at 10°C and 2 atm carbon dioxide is below the triple point, the only way to convert it into liquid is by increasing the pressure (moving up in the vertical direction).
The temperature is the same but the heat flow is the opposite.
Propylethylene would be the answer