Which elements do not have a set number of valence electrons?

Many double-displacement reactions are enzyme-catalyzed via the "ping pong" mechanism, so called because the reactants appear to

zhenek [66]

Answer:

D. It will decrease by a factor of 4

Explanation:

According to the question , the equation follows :

$A+B\rightarrow C+D$

Rate law : This states the rate of reaction is directly proportional to concentration of reactants with each reactant raised to some power which may or may not be equal to the stoichiometeric coefficient.

$Rate\ \alpha [A]^{a}[B]^{b}$

$r=[A]^{a}[B]^{b}$ .................(1)

STEP": First, find out the power "a" and "b"

a+b = 3 (because it is given that the reaction follow 3rd order-kinetics)

According to question, doubling the concentration of the first reactant causes the rate to increase by a factor of 2 means,

r' = 2r if [A'] = 2[A]

Here [B] is uneffected means [B']=[B]

hence new rate =

$r'=[A']^{a}[B']^{b}$

Put the value of [A'] , [B'] and r' in the above equation:

$2r=[2A]^{a}[B]^{b}$ ...........(2)

Divide equation (1) by (2) we , get

$\frac{2r}{r}=\frac{[2A]^{2}[B]^{b}}{[A]^{a}[B]^{b}}$

$2= 2(\frac{A}{A})^{a}\times (\frac{B}{B})^{b}$

Here A and A cancel each other

B and B cancel each other

We get,

$2= 2^{a}\times 1^{b}$

1^b = 1 ( power of 1 = 1)

$2= 2^{a}$

This is possible only when a = 1

We know that : a + b = 3

1 + b = 3

b =3 -1 = 2

b = 2

Hence the rate law becomes :

$r=[A]^{a}[B]^{b}$

$r=[A]^{1}[B]^{2}$ .............(3)

Look in the question now, it is asked to calculate the concentration of [B],if cut in half

Hence

[B']=1/2[B]

Insert the value of [B'] in equation (3)

$r'=[A]^{1}[B']^{2}$

$r'=[A]^{1}(\frac{1}{2}[B])^{2}$

$r'=\frac{1}{4}[A]^{1}[B]^{2}$ ............(a)

But

$r=[A]^{a}[B]^{b}$ ..............(b)

Compare equation (a) and (b) , we get

new rate r' =

r' = 1/4 r

7 0

3 years ago

What does heat, enthalpy, entropy and free energy all have in common

vekshin1

Answer: Free energy combined enthalpy and entropy into a single value. Gibbs’s free energy is the energy associated with a chemical reaction that can do useful work. It equals the enthalpy minus the product of temperature and entropy of the system.

Explanation:

4 0

3 years ago

Write the equilibrium constant expression for the following reaction in terms of concentrations of the components. (Concentratio

timofeeve [1]

Answer: The expression for equilibrium constant in terms of concentration is $K_c=[CO_2]$

Explanation:

Equilibrium constant in terms of concentration is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric coefficients. It is represented by $K_{c}$