This question is describing two chemical equations whereby the concentration of ammonia has to be determined. The first reaction is between 25.00 mL of ammonia and 50.00 mL of 0.100-M HCl whose excess was neutralized with 21.50 mL of 0.050-M Na₂CO₃ and thus, the concentration ammonia in the cloudy solution was determined as 0.114 M.
First of all we need to go over the titration of the excess HCl with Na₂CO₃ by writing the chemical equation it takes place when they react:
Whereas the mole ratio of HCl to Na₂CO₃ is 2:1 and the volume of the HCl leftover is determined as follows:
Next, we infer that the consumed volume of HCl by the ammonia solution was:
Then, we write the chemical equation that takes place between ammonia and HCl:
Whereas the mole ratio is now 1:1, which means that the concentration of ammonia was:
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