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3 years ago

What set of coefficients will balance the chemical equation: _NaBr (aq) + _H3PO4 (aq) → _Na3PO4(aq) + _HBr (aq)

Chemistry

1 answer:

GaryK [48]3 years ago

6 0

The Balanced chemical equation for above reaction will be :

$\small{ \mathrm{3NaBr + H_3PO_4 \rightarrow Na_3PO_4 + 3HBr}}$

The Coefficients will be :

$NaBr - 3$

$H_3PO_4 - 1$

$Na_3PO_4 - 1$

$HBr - 3$

So, Correct option is :

A. 3, 1, 1, 3

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Calculate the standard reaction Gibbs free energy for the following cell reactions: (a) 2 Ce41(aq) 1 3 I2(aq) S 2 Ce31(aq) 1 I32

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Answer:

For a: The standard Gibbs free energy of the reaction is -347.4 kJ

For b: The standard Gibbs free energy of the reaction is 746.91 kJ

Explanation:

Relationship between standard Gibbs free energy and standard electrode potential follows:

$\Delta G^o=-nFE^o_{cell}$ ............(1)

For a:

The given chemical equation follows:

$2Ce^{4+}(aq.)+3I^{-}(aq.)\rightarrow 2Ce^{3+}(aq.)+I_3^-(aq.)$

Oxidation half reaction: $Ce^{4+}(aq.)\rightarrow Ce^{3+}(aq.)+e^-$ ( × 2)

Reduction half reaction: $3I^_(aq.)+2e^-\rightarrow I_3^-(aq.)$

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$n=2\\E^o_{cell}=+1.08V\\F=96500$

Putting values in equation 1, we get:

$\Delta G^o=-2\times 96500\times (+1.80)=-347,400J=-347.4kJ$

Hence, the standard Gibbs free energy of the reaction is -347.4 kJ

For b:

The given chemical equation follows:

$6Fe^{3+}(aq.)+2Cr^{3+}+7H_2O(l)(aq.)\rightarrow 6Fe^{2+}(aq.)+Cr_2O_7^{2-}(aq.)+14H^+(aq.)$

Oxidation half reaction: $Fe^{3+}(aq.)\rightarrow Fe^{2+}(aq.)+e^-$ ( × 6)

Reduction half reaction: $2Cr^{2+}(aq.)+7H_2O(l)+6e^-\rightarrow Cr_2O_7^{2-}(aq.)+14H^+(aq.)$

We are given:

$n=6\\E^o_{cell}=-1.29V\\F=96500$

Putting values in equation 1, we get:

$\Delta G^o=-6\times 96500\times (-1.29)=746,910J=746.91kJ$

Hence, the standard Gibbs free energy of the reaction is 746.91 kJ

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