Ways of preventing rusting
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Answer :
(a) 1.000 g of compound containing carbon and hydrogen is, 0.922 g and 0.0769 g respectively.
(b) There is no other element present in the compound.
Explanation :
(a) Now we have to determine the masses of C and H in the sample.
The chemical equation for the combustion of hydrocarbon having carbon, hydrogen and oxygen follows:
where, 'x' and 'y' are the subscripts of Carbon and hydrogen respectively.
We are given:
Mass of
Mass of
We know that:
Molar mass of carbon dioxide = 44 g/mol
Molar mass of water = 18 g/mol
For calculating the mass of carbon:
In 44 g of carbon dioxide, 12 g of carbon is contained.
So, in 3.381 g of carbon dioxide, of carbon will be contained.
For calculating the mass of hydrogen:
In 18 g of water, 2 g of hydrogen is contained.
So, in 0.692 g of water, of hydrogen will be contained.
Thus, 1.000 g of compound containing carbon and hydrogen is, 0.922 g and 0.0769 g respectively.
(b) Now we have to determine the compound contain any other elements or not.
Mass carbon + Mass of hydrogen = 0.922 g + 0.0769 g = 0.999 g ≈ 1 g
This means that there is no other element present in the compound.
Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.
