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Ch.2 - Atoms & ElementsSee all chapters
Atomic Theory
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Solution: Which of the following chemical reactions is/are NOT possible according to Dalton's atomic theory?a. reaction 1: CCl4 → CH4b. reaction 2: N2 + 3H2 → 2NH3c. reaction 3: 2H2 + O2 → 2H2O + Au
Problem
Which of the following chemical reactions is/are NOT possible according to Dalton's atomic theory?
a. reaction 1: CCl4 → CH4
b. reaction 2: N2 + 3H2 → 2NH3
c. reaction 3: 2H2 + O2 → 2H2O + Au
Answer:
Final molarity of iodide ion C(I-) = 0.0143M
Explanation:
n = (m(FeI(2)))/(M(FeI(2))
Molar mass of FeI(3) = 55.85+(127 x 2) = 309.85g/mol
So n = 0.981/309.85 = 0.0031 mol
V(solution) = 150mL = 0.15L
C(AgNO3) = 35mM = 0.035M = 0.035m/L
n(AgNO3) = C(AgNO3) x V(solution)
= 0.035 x 0.15 = 0.00525 mol
(AgNO3) + FeI(3) = AgI(3) + FeNO3
So, n(FeI(3)) excess = 0.00525 - 0.0031 = 0.00215mol
C(I-) = C(FeI(3)) = [n(FeI(3)) excess]/ [V(solution)] = 0.00215/0.15 = 0.0143mol/L or 0.0143M
In the question, the number of atoms per unit cell is required for:
A) Polonium (Po)
In polonium, the structure is simple cubic, meaning there are 8 corner atoms, which add up to one atom per unit cell.
B) Manganese (Mn)
The structure of the Mn can be considered to be a body centered cubic (BCC) and the number of atoms for this is 8 corner atoms and 1 central atoms, making a total of 2 atoms per unit cell.
C) Silver (Ag)
Silver has a face centered cubic (FCC) unit cell structure, where there are 8 corner atoms and 6 atoms on the faces, so there are a total of 4 atoms per unit cell.