Answer:
What give me a few minutes I have to finish my test them I will answer in comments.
<h2>♨ANSWER♥</h2>
pl (25*C)
Arginine -----> 10.76
Glutamic -----> 3.08
Asparagine -----> 5.43
Tyrosine -----> 5.63
<u>☆</u><u>.</u><u>.</u><u>.</u><u>hope this helps</u><u>.</u><u>.</u><u>.</u><u>☆</u>
_♡_<em>mashi</em>_♡_
Answer : The value of rate constant is, 
Explanation :
First we have to calculate the rate constant, we use the formula :
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = ?
t = time passed by the sample = 20 min
a = let initial amount of the reactant = 100 g
a - x = amount left after decay process = 100 - 85 = 15 g
Now put all the given values in above equation, we get


Therefore, the value of rate constant is, 
The concentration of the hydronium ion in hydrochloric acid is 0.0045 M, and the pH of the solution is 2.34.
<h3>What is pH?</h3>
pH is the potential of the hydrogen or the hydronium ions in the aqueous solution.
As the solution contains
HCl the concentration of the hydronium ion will be the same, 
The pH of the solution is calculated as:
![\begin{aligned} \rm pH &= \rm -log[H^{+}]\\\\&= - \rm log (4.5 \times 10^{-3})\\\\&= 2.34\end{aligned}](https://tex.z-dn.net/?f=%5Cbegin%7Baligned%7D%20%5Crm%20pH%20%26%3D%20%5Crm%20-log%5BH%5E%7B%2B%7D%5D%5C%5C%5C%5C%26%3D%20-%20%5Crm%20log%20%284.5%20%5Ctimes%2010%5E%7B-3%7D%29%5C%5C%5C%5C%26%3D%202.34%5Cend%7Baligned%7D)
The concentration of the hydroxide ion is calculated from pH and hydronium ion as:
![\begin{aligned} \rm [H_{3}O^{+}][OH^{-}] &= 10^{-14}\\\\&= \dfrac{1 \times 10^{-14}}{4.5 \times 10^{-3}}\\\\&= 2.2 \times 10^{12}\end{aligned}](https://tex.z-dn.net/?f=%5Cbegin%7Baligned%7D%20%5Crm%20%5BH_%7B3%7DO%5E%7B%2B%7D%5D%5BOH%5E%7B-%7D%5D%20%26%3D%2010%5E%7B-14%7D%5C%5C%5C%5C%26%3D%20%5Cdfrac%7B1%20%5Ctimes%2010%5E%7B-14%7D%7D%7B4.5%20%5Ctimes%2010%5E%7B-3%7D%7D%5C%5C%5C%5C%26%3D%202.2%20%5Ctimes%2010%5E%7B12%7D%5Cend%7Baligned%7D)
Now, for the calcium hydroxide solution, the calculations are shown as,

pOH is calculated as:
![\begin{aligned} \rm pOH &= 14- 8 = 6\\\\\rm [OH^{-}] &= \rm antilog (-6)\\\\&= 10^{-6} \end{aligned}](https://tex.z-dn.net/?f=%5Cbegin%7Baligned%7D%20%5Crm%20pOH%20%26%3D%2014-%208%20%3D%206%5C%5C%5C%5C%5Crm%20%5BOH%5E%7B-%7D%5D%20%26%3D%20%20%5Crm%20antilog%20%28-6%29%5C%5C%5C%5C%26%3D%2010%5E%7B-6%7D%20%5Cend%7Baligned%7D)
The concentration of calcium hydroxide is calculated as:
![\begin{aligned} &= \dfrac{1}{2} \times \rm [OH^{-}]\\\\&= 5 \times 10^{-4} \;\rm M\end{aligned}](https://tex.z-dn.net/?f=%5Cbegin%7Baligned%7D%20%26%3D%20%5Cdfrac%7B1%7D%7B2%7D%20%5Ctimes%20%5Crm%20%5BOH%5E%7B-%7D%5D%5C%5C%5C%5C%26%3D%205%20%5Ctimes%2010%5E%7B-4%7D%20%5C%3B%5Crm%20M%5Cend%7Baligned%7D)
Therefore, the pH and the pOH give the concentration of the hydrogen or the hydronium ion and the hydroxide ion.
Learn more about pH and pOH here:
brainly.com/question/16062632
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A chemical change occurs when the identity of a substance is changed. Silver tarnishing is a chemical change because silver and sulfur react to form a new substance, silver sulfide. In the other examples, the substances have not changed their identity and only physical changes have occurred. the correct answer is D