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BartSMP [9]
4 years ago
15

Ethoxide ion is a base that can remove an acidic proton in an α-position to a carbonyl group. The resulting enolate ion is a nuc

leophile. What electrophilic site will it attack?
Chemistry
1 answer:
german4 years ago
4 0

Answer:

The electrophilic site that it will attack will be the carbonyl carbon

Explanation:

Assuming that in the solution there is excess of carbonyl group attached compound

As ethoxide ion is a strong base, it can remove an acidic proton in an α-position to a carbonyl group

The resulting compound will be an enolate ion and in enolate ion the centre of attacking will be the carbon and as there is negative charge on the carbon, it will get stabilized because of resonance and - I effect of carbonyl group

As the negative charge on the carbon can be stabilized by resonance, it will be a weak base when compared to ethoxide ion but it has more nucleophilic character when compared to ethoxide ion because in polar solvents there will be solvation effect on ethoxide ion

The electrophilic site is the position where there will be partial positive charge and in this case the electrophilic site will be the carbon in carbonyl group attached compound because of - I effect of sp_{2} oxygen it will gain partial positive charge

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