Take note of the subscript written for each element in the compound. To find the total number of moles, make sure to multiply the subscript with the number of moles of compound. The answer for each is written below:
a. 3*1 = 3 moles Nitrogen; 3*3 = 9 moles Hydrogen
b. 0.25*2 = 0.5 moles Hydrogen; 0.25*1 = 0.25 moles Oxygen
c. 5*2 = 10 moles Hydrogen; 5*1 =5 moles Sulfur; 5*4 = 20 moles Oxygen
d. 0.75*1 = 0.75 moles Calcium; 0.75*1*2 = 1.5 moles Nitrogen; 0.75*3*2 = 4.5 moles Oxygen
The answer is catalyst.
A catalyst is characterized by acceleration the rate of a chemical reaction but not modifiy the equilibrium, which is what k represents (the constant of equilibrium of the reaction).
The catalyst manages that the reaction goes through a different pathway, with a lower activation energy, so the transition compound is reached faster and the whole reaction goes faster, but the final species and their equilibriium concentrations do not change.