It is a 1 in 13 chance of drawing at least 1 ace.
800,000,000,000 + 20,000,000,000 + 3,000,000,000 + 50,000,000 + 4,000,000 + 600,000 + 50,000 + 8,000 + 700 + 80 + 6
WITCHER [35]
823054658786 is the answer to your question
Psi stands for pounds per square-inch.
It is a measure of pressure, and is the equivalent pressure of putting one pound on a square-inch of area.
For example, someone weighing 180 pounds standing on his feet, with a footprint area of 72 square-inches would exert a pressure of 180 pounds/72 square inches = 2.5 pounds per square-inch, or 2.5 psi.