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1 answer:
Answer: The volume occupied at an altitude of 20.0 km is 34.5289 L
Explanation:
Boyle's Law: This law states that pressure is inversely proportional to the volume of the gas at constant temperature and number of moles.
(At constant temperature and number of moles)
where,
= initial pressure of gas = 101.325 kPa ( sea level)
= final pressure of gas = 10 kPa
= initial volume of gas = 3.40774 L
= final volume of gas = ?
Now put all the given values in the above equation, we get the final pressure of gas.
Therefore, the volume occupied at an altitude of 20.0 km is 34.5289 L
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Question is incomplete, complete question is as follows :
Complete Question : .Sulfonation of benzene has the following mechanism:
(1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3
[fast]
(2) SO3 + C6H6 → H(C6H5+)SO3−
[slow]
(3) H(C6H5+)SO3− + HSO4− → C6H5SO3− + H2SO4
[fast]
(4) C6H5SO3− + H3O+ → C6H5SO3H + H2O
[fast]
write the overall rate law for the initial rate of the reaction as a fraction.
Rate=k(________/_________)
Answer:
The overall rate law for the initial reaction is =
Explanation :
Frist of all, all the common terms are cancelled out and written the overall reaction.
As we know that the rate depednant step is the slowest step of the reaction, rate law is :
rate =
But the problem is that SO3 cannot be written in the overall rate law because it is an intermediate.
Rate law for synthesis of S03 is as follows :
rate =
Hence when we substitute equation 2 in equation one,
Rate comes out to be =