S₂O₈²⁻
(aq) + 2I⁻
(aq) → I₂(aq) + 2SO₄
²⁻(aq)
2S₂O₃²⁻
(aq) + I₂(aq) → S₄O₆²⁻
(aq) + 2I⁻
(aq)
<u>Explanation:</u>
S₂O₈²⁻
(aq) + 2I⁻
(aq) → I₂(aq) + 2SO₄
²⁻(aq)
To measure the rate of this reaction we must measure the rate of concentration change of one of the reactants or products. To do this, we will include (to the reacting S₂O₈
²⁻ and I⁻
i) a small amount of sodium thiosulfate, Na₂S₂O₃,
ii) some starch indicator.
The added Na₂S₂O₃ does not interfere with the rate of above reaction, but it does consume the I₂ as soon as it is formed.
2S₂O₃²⁻
(aq) + I₂(aq) → S₄O₆²⁻
(aq) + 2I⁻
(aq)
This reaction is much faster than the previous, so the conversion of I2 back to I⁻ is essentially instantaneous.
![rate = \frac{dI2}{dt} = \frac{1/2 [S2O3^2^-]}{t}](https://tex.z-dn.net/?f=rate%20%3D%20%5Cfrac%7BdI2%7D%7Bdt%7D%20%3D%20%5Cfrac%7B1%2F2%20%5BS2O3%5E2%5E-%5D%7D%7Bt%7D)
1) in periodic acid (HIO₄), iodine has oxidation number +7, hydrogen has oxidation number +1, oxygen has -2, compound has neutral charge:
+1 + x + 4 · (-2) = 0.
x = +7.
2) in molecule of iodine (I₂), iodine has oxidation number 0, because iodine is nonpolar molecule.
3) in sodium iodide (NaI), iodine has oxidation number -1, sodium has oxidation number +1:
+1 + x = 0.
x = -1.
4) in iodic acid (HIO₃), iodine has oxidation number +5, hydrogen has oxidation number +1, oxygen has -2, compound has neutral charge:
+1 + x + 3 · (-2) = 0.
x = +5.
Answer:
B
Explanation:
The particles are bound to each other and they vibrate at an almost undetectable rate.
Write a balance equation for the reaction between the analyte and the titrant.
Calculate the # of moles of titrant using the volume of titrant required and the concentration of titrant.
Calculate the # of moles of analyte using the stoichiometric coefficients of the equation.
Calculate the concentration of the analyte using the number or moles of analyte and the volume of analyte titrated.
