Answer:
1/16 = 0.0625 = 6.25% probability that the sum of the two rolls equals 5.
Step-by-step explanation:
A probability is the number of desired outcomes divided by the number of total outcomes.
Die with 8 sides
This means that the total number of outcomes is 
Outcomes in which the sum of the two rolls is 5:
(1,4), (4,1), (2,3), (3,2)
4 desired outcomes, so 
What is the probability that the sum of the two rolls equals 5?

1/16 = 0.0625 = 6.25% probability that the sum of the two rolls equals 5.