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Calculate the final temperature of a mixture of 0.350 kg of ice initially at 218°C and 237 g of water initially at 100.0°C.

kramer

Answer:

115 ⁰C

Explanation:

Step 1: The heat needed to melt the solid at its melting point will come from the warmer water sample. This implies

$q_{1} +q_{2} =-q_{3}$ -----eqution 1

where,

$q_{1}$ is the heat absorbed by the solid at 0⁰C

$q_{2}$ is the heat absorbed by the liquid at 0⁰C

$q_{3}$ the heat lost by the warmer water sample

Important equations to be used in solving this problem

$q=m *c*\delta {T}$ , where -----equation 2

q is heat absorbed/lost

m is mass of the sample

c is specific heat of water, = 4.18 J/0⁰C

$\delta {T}$ is change in temperature

Again,

$q=n*\delta {_f_u_s}$ -------equation 3

where,

q is heat absorbed

n is the number of moles of water

tex]\delta {_f_u_s}[/tex] is the molar heat of fusion of water, = 6.01 kJ/mol

Step 2: calculate how many moles of water you have in the 100.0-g sample

$=237g *\frac{1 mole H_{2} O}{18g} = 13.167 moles of H_{2}O$

Step 3: calculate how much heat is needed to allow the sample to go from solid at 218⁰C to liquid at 0⁰C

$q_{1} = 13.167 moles *6.01\frac{KJ}{mole} = 79.13KJ$

This means that equation (1) becomes

79.13 KJ + $q_{2} = -q_{3}$

Step 4: calculate the final temperature of the water

$79.13KJ+M_{sample} *C*\delta {T_{sample}} =-M_{water} *C*\delta {T_{water}$

Substitute in the values; we will have,

$79.13KJ + 237*4.18\frac{J}{g^{o}C}*(T_{f}-218}) = -350*4.18\frac{J}{g^{o}C}*(T_{f}-100})$

79.13 kJ + 990.66J* $(T_{f}-218})$ = -1463J* $(T_{f}-100})$

Convert the joules to kilo-joules to get

79.13 kJ + 0.99066KJ* $(T_{f}-218})$ = -1.463KJ* $(T_{f}-100})$

$79.13 + 0.99066T_{f} -215.96388= -1.463T_{f}+146.3$

collect like terms,

2.45366 $T_{f}$ = 283.133

∴ $T_{f} =$ = 115.4 ⁰C

Approximately the final temperature of the mixture is 115 ⁰C

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We are given that,

$\frac{dx}{dt} = 4ft/s$

We need to find $\frac{d\theta}{dt}$ when $x=8ft$

The equation that relates x and $\theta$ can be written as,

$\frac{x}{6} tan\theta$

$x = 6tan\theta$

Differentiating each side with respect to t, we get,

$\frac{dx}{dt} = \frac{dx}{d\theta} \cdot \frac{d\theta}{dt}$

$\frac{dx}{dt} = (6sec^2\theta)\cdot \frac{d\theta}{dt}$

$\frac{d\theta}{dt} = \frac{1}{6sec^2\theta} \cdot \frac{dx}{dt}$

Replacing the value of the velocity

$\frac{d\theta}{dt} = \frac{1}{6} cos^2\theta (4)^2$

$\frac{d\theta}{dt} = \frac{8}{3} cos^2\theta$

The value of $cos \theta$ could be found if we know the length of the beam. With this value the equation can be approximated to the relationship between the sides of the triangle that is being formed in order to obtain the numerical value. If this relation is known for the value of x = 6ft, the mathematical relation is obtained. I will add a numerical example (although the answer would end in the previous point) If the length of the beam was 10, then we would have to

$cos\theta = \frac{6}{10}$

$\frac{d\theta}{dt} = \frac{8}{3} (\frac{6}{10})^2$

$\frac{d\theta}{dt} = \frac{24}{25}$

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