Physical changes are when things get changed without altering chemical consistencies, which is melting solid butter into liquid one, or boiling water. Chemical changes are things such as caramelizing sugar when making sweets, or when carbon dioxide is created and released when baking bread.
C. or A. Is your best bet
We have Kc = 4.2 x 10^-2 (given but missing in the question)
and When the balanced equation for this reaction is:
PCl5(g) ↔ PCl3(g) + Cl2(g)
so, according to the Kc formula:
Kc = the concentration of products / the concentration of the reactants
so, to get the concentration of the reactants in equilibrium, the concentration of the products / the concentration of the reactants should equal the Kc value which is given in the question (missing in your question).
So by substitution in Kc formula:
Kc = [PCl3]*[Cl2] / [PCl5]
4.2 x 10^-2 = 0.18 * 0.25 /[PCl5]
∴[PCl5] = 0.18*0.25 / 4.2x10^-2 = 1.07
So the concentration of the reactants in equilibrim = 1.07