Answer:
Cement is a combination of calcium, silicone, aluminum, iron and lots of other ingredients to make side walks, home made crafts, etc. The person who invented concrete is Joseph Aspdin.
Explanation:
Answer: Option (d) is the correct answer.
Explanation:
Steps involved for the given reaction will be as follows.
Step 1: 
(fast)
Rate expression for step 1 is as follows.
Rate = k ![[NO]^{2}](https://tex.z-dn.net/?f=%5BNO%5D%5E%7B2%7D)
Step 2: 
This step 2 is a slow step. Hence, it is a rate determining step.
Step 3. 
(fast)
Here, 
is intermediate in nature.
All the steps are bimolecular and it is a second order reaction. Also, there is no catalyst present in this reaction.
Thus, we can conclude that the statement step 1 is the rate determining step, concerning this mechanism is not directly supported by the information provided.
The given solution of Mn²⁺ is 0.60 mg/mL.
Hence mass of Mn²⁺ in 5 mL of solution = 0.60 mg/mL x 5 mL = 3 mg
Molar mass of Mn = 54.9 g/mol
Hence, moles of Mn²⁺ = 3 x 10⁻³ g / 54.9 g/mol = 5.46 x 10⁻⁵ mol
The balanced equation for the reaction is,
2Mn²⁺ + 5KIO₄ + 3H₂O → 2MnO₄⁻ + 5KIO₃ + 6H⁺
The stoichiometric ratio between Mn²⁺ and KIO₄ is 2 : 5
Hence, moles of KIO₄ reacted = 5.46 x 10⁻⁵ mol x (5 / 2)
= 13.65 x 10⁻⁵ mol
Molar mass of KIO₄ = 230 g/mol
Hence needed mass of KIO₄ = 13.65 x 10⁻⁵ mol x 230 g/mol
= 0.031395 g
= 31.395 mg
≈ 31.4 mg
