Initial volume of the balloon = 
= 348 mL
Initial temperature of the balloon 
= 
Final volume of the balloon 
= 322 mL
Final temperature of the balloon = 
According to Charles law, volume of an ideal gas is directly proportional to the temperature at constant pressure.
On plugging in the values,
Therefore, the temperature of the freezer is 276 K
kilograms are the unit that measures mass
With all of the information given (pressure, volume, temperature, and the molar mass), we need a formula that relates this all together. The formula we need is the ideal gas law, PV=nRT. Since the pressure is defined in millimeters of mercury, we need the R value that correlates with this, which is 62.4; on top of this, we need the temperature in Kelvin - simply add 273.15 to convert from Celsius. With all of this information, simply plug-and-chug:
PV=nRT
(800)(3.7) = n(62.4)(37 + 273.15)
n = 0.1529 moles
Finally, the problem is asking the amount of air in grams. We have moles, so all we need to do is multiply that value by the molar mass.
0.1529 moles x 29 grams per mole =
4.435 grams of air
The balloon has 4.435 grams of air inside it.
Hope this helps!
