Bohr model is valid only for hydrogen and hydrogen-like species, but quantum mechanical model can explain all elements....
So we look equation for the free Gibbs free energy (ΔG) which depends on entalpy (ΔH), temperature (T) and entropy (ΔS):
ΔG = ΔH - TΔS
ΔG is negative (-) because the water absorption on the silica gel surface is a spontaneous process.
ΔH is negative (-) because the water absorption on the silica gel surface is a exothermic process (it releases heat and if you want to desorb the water form the silica gen you need to add heat which is a endothermic process).
ΔS is negative (-) because the water is adsorbed, so from disorderly state you take the water molecules and put them in a orderly state and by doing that you decrease the entropy.
Use the formula for second order reaction:

C = concentration at time t
C0 = initial conc.
k = rate constant
t = time
1st equation :

2nd Equation:

Find

from 1st equation and put it in 2nd equation:


k = 0.046
Answer:
C. Tip had the lower pressure, it was 652.71mmHg
Explanation:
To answer this question you need to convert both values into a common unit so you can compare directly.
87kPa = 652.71 mmHg