Answer:
A = 674.33mmHg
B = 0.385atm
Explanation:
Both question A and B requires the application of pressure law which states that the pressure of a fixed mass of gas is directly proportional to its temperature provided that volume is kept constant.
Mathematically,
P = kT, k = P / T
P1 / T1 = P2 / T2 = P3 / T3 =.......= Pn/Tn
A)
Data:
P1 = 799mmHg
T1 = 50°C = (50 + 273.15) = 323.15K
P2 = ?
T2 = 273.15K
P1 / T1 = P2 / T2
Solve for P2
P2 = (P1 × T2) / T1
P2 = (799 × 273.15) / 323.15
P2 = 674.37mmHg
The final pressure is 674.37mmHg
B)
P1 = 0.470atm
T1 = 60°C = (60 + 273.15)K = 333.15K
P2 = ?
T2 = 273.15K
P1 / T1 = P2 / T2
Solve for P2,
P2 = (P1 × T2) / T1
P2 = (0.470 × 273.15) / 333.15
P2 = 0.385atm
The final pressure is 0.385atm
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Answer: 
Explanation:
According to the Arrhenius equation,

or,
![\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7BK_1%7D%29%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= rate constant at
= 
= rate constant at
= 
= activation energy for the reaction = 262 kJ/mol = 262000J/mol
R = gas constant = 8.314 J/mole.K
= initial temperature = 
= final temperature = 
Now put all the given values in this formula, we get
![\log (\frac{6.1\times 10^{-8}}{K_2})=\frac{262000}{2.303\times 8.314J/mole.K}[\frac{1}{600.0K}-\frac{1}{775.0K}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7B6.1%5Ctimes%2010%5E%7B-8%7D%7D%7BK_2%7D%29%3D%5Cfrac%7B262000%7D%7B2.303%5Ctimes%208.314J%2Fmole.K%7D%5B%5Cfrac%7B1%7D%7B600.0K%7D-%5Cfrac%7B1%7D%7B775.0K%7D%5D)


Therefore, the value of the rate constant at 775.0 K is 
3NF3 + 5H2O → HNO3 + 2NO + 9HF
Nitrogen fluoride reacts with water to produce nitric acid, nitric oxide, and hydrogen fluoride. The reaction slowly takes place in a boiling solution.
CH2CH2 + H2O → CH3CH2OH
Ethylene is a hydrocarbon with water that creates ethanol and ethanol is an alcohol