Answer:
By a factor of 12
Explanation:
For the reaction;
A + 2B → products
The rate law is;
rate = k[A]²[B]
As you can see, the rate is proportional to the square of the concentration of A and the of the concentration of B
.
Let's say initially, [A] = x, [B] = y
The rate law in this case is equal to;
rate1 = k. x².y
Now you double the concentration of A and triple the concentration of B.
[A] = 2x, [B] = 3y
The new rate law is given as;
rate2 = k . (2x)². (3y)
rate2 = k . 4x² . 3y
rate2 = 12 k . x² . y
Comparing rate 2 and rate 1, the ratio is given as; rate 2/ rate 1 = 12
Therefore the rate has increased by a factor of 12.
Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
<em />
<span>2AlPO4 ( aq) + 3MgCl2 (aq) -> Mg3(PO4)2 (s) + 2AlCl3 (aq) </span>
<span>Right answer is D
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