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3 years ago

5

1. Consider the peptide with amino acid sequence NICE. Write the full name and the three-letter abbreviations of the amino acids

in the peptide (8 marks)
b. Calculate the net charge of the peptide at pH 7.0. Show you work in a table. In the table, you don't need to write “protonated” or “deprotonated"; just write “O”, "P" or ““ to indicate the charge. Step marks are counted. (3 marks)

c. Calculate the pl of the peptide. Show you work in a table. Step marks are counted. (6 marks)

1 answer:

Alex Ar [27]3 years ago

6 0

Answer:

I think its c i did a lil research

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<u>Answer:</u> The amount of heat produced by the reaction is -21.36 kJ

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Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles.

The equation used to calculate enthalpy change is of a reaction is:

$\Delta H^o_{rxn}=\sum [n\times \Delta H_f_{(product)}]-\sum [n\times \Delta H_f_{(reactant)}]$

For the given chemical reaction:

$2SO_2(g)+O_2(g)\rightarrow 2SO_3(g)$

The equation for the enthalpy change of the above reaction is:

$\Delta H_{rxn}=[(2\times \Delta H_f_{(SO_3(g))})]-[(2\times \Delta H_f_{(SO_2(g))})+(1\times \Delta H_f_{(O_2(g))})]$

We are given:

$\Delta H_f_{(SO_2(g))}=-296.8kJ/mol\\\Delta H_f_{(SO_3(g))}=-395.7kJ/mol\\\Delta H_f_{(O_2(g))}=0kJ/mol$

Putting values in above equation, we get:

$\Delta H_{rxn}=[(2\times (-395.7))]-[(2\times (-296.8))+(1\times (0))]\\\\\Delta H_{rxn}=-197.8kJ/mol$

To calculate the number of moles, we use ideal gas equation, which is:

$PV=nRT$

where,

P = pressure of the gas = 1.00 bar

V = Volume of the gas = 2.67 L

n = number of moles of gas = ?

R = Gas constant = $0.0831\text{ L. bar }mol^{-1}K^{-1}$

T = temperature of the mixture = $25^oC=[25+273]K=298K$

Putting values in above equation, we get:

$1.00bar\times 2.67L=n\times 0.0831\text{ L. bar }mol^{-1}K^{-1}\times 298K\\\\n=\frac{1\times 2.67}{0.0831\times 298}=0.108mol$

To calculate the heat released of the reaction, we use the equation:

$\Delta H_{rxn}=\frac{q}{n}$

where,

q = amount of heat released = ?

n = number of moles = 0.108 moles

$\Delta H_{rxn}$ = enthalpy change of the reaction = -197.8 kJ/mol

Putting values in above equation, we get:

$-197.8kJ/mol=\frac{q}{0.108mol}\\\\q=(-197.8kJ/mol\times 0.108mol)=-21.36kJ$

Hence, the amount of heat produced by the reaction is -21.36 kJ

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