Answer:
(a) 77.9 g/mol
(b) 3.18 g / L
Explanation:
<u>(a)</u> We need to use the ideal gas law, which states: PV = nRT, where P is the pressure, V is the volume, n is the moles, R is the gas constant, and T is the temperature in Kelvins.
Notice that we don't have moles; we instead have the mass. Remember, though that moles can be written as m/M, where m is the mass and M is the molar mass. So, we can replace n in the equation with m/M, or 21.3/M. The components we now have are:
- P: 0.880 atm
- V: 7.73 Litres
- n: m/M = 21.3 g / M
- R: 0.08206
- T: 30.00°C + 273 = 303 K
Plug these in:
PV = nRT
(0.880)(7.73) = (21.3/M)(0.08206)(303)
Solve for M:
M = 77.9 g/mol
<u>(b)</u> The equation for the molar mass is actually:
M = (dRT)/P, where d is the density
We have all the components except d, so plug them in:
77.9 = (d * 0.08206 * 298) / 1
Solve for d:
d = 3.18 g / L
There should be 22 figures .
Answer:
Q sln = 75.165 J
Explanation:
a constant pressure calorimeter:
∴ m sln = m Ba(OH)2 + m HCl
∴ molar mass Ba(OH)2 = 171.34 g/mol
∴ mol Ba(OH)2 = (0.06 L)(0.3 mol/L) = 0.018 mol
⇒ mass Ba(OH)2 = (0.018 mol)(171.34 g/mol) = 3.084 g
∴ molar mass HCl = 36.46 g/mol
∴ mol HCl = (0.06 L)(0.60 mol/L) = 0.036 mol
⇒ mass HCl = (0.036 mol)(36.46 g/mol) = 1.313 g
⇒ m sln = 3.084 g + 1.313 g = 4.3966 g
specific heat (C):
∴ C sln = C H2O = 4.18 J/g°C
∴ ΔT = 26.83°C - 22.74°C = 4.09°C
heat absorbed (Q):
⇒ Q sln = (4.3966 g)(4.18 J/g°C)(4.09°C)
⇒ Q sln = 75.165 J
Answer: C) 
Explanation: The <u>Valence</u> <u>Shell</u> <u>Electron</u> <u>Pair</u> <u>Repulsion</u> <u>Model</u> (VSEPR Model) shows bonding and nonbonding electron pairs present in the valence, outermost, shell of an atom connecting to other atoms. It also gives the molecular geometric shape of a molecule.
To determine molecular geometry:
1) Draw Lewis Structure, i.e., a simplified representation of the valence shell electrons;
2) Count the number of electron pairs (count multiple bonds as 1 pair);
3) Arrange electron pairs to minimise repulsion;
4) Position the atoms to minimise the lone pair;
5) Name the molecular geometry from the atom position;
Trigonal planar molecular geometry is a model which molecule's shape is triangular and in one plane. Such molecule has three regions of electron density extending out from the central atom and the repulsion will be at minimum when angle between any two is 120°.
The Lewis structure of each molecule is shown in the attachment.
<u>Analysing each one, it can be concluded that molecule with trigonal planar geometry is </u>
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