Outdoor pollution primarily results from the combustion of fossil fuels by industrial plants and vehicles. This releases carbon monoxide, sulfur dioxide, particulate matter, nitrogen oxides, hydrocarbons and other pollutants.
Answer is: boiling point will be changed by 4°C.
Chemical dissociation of aluminium nitrate in water: Al(NO₃)₃ → Al³⁺(aq) + 3NO⁻(aq).
Change in boiling point: ΔT =i · Kb · b.
Kb - molal boiling point elevation constant of water is 0.512°C/m, this the same for both solution.
b - molality, moles of solute per kilogram of solvent., this is also same for both solution, because ther is same amount of substance.
i - Van't Hoff factor.
Van't Hoff factor for sugar solution is 1, because sugar do not dissociate on ions.
Van't Hoff factor for aluminium nitrate solution is approximately 4, because it dissociates on four ions (one aluminium cation and three nitrate anions). So ΔT is four times bigger.
<em>K</em> = 2.4 × 10^(-72)
<em>Step 1</em>. Determine the <em>value of n
</em>
Zn^(2+) + 2e^(-) → Zn
2Cl^(-) → Cl_2 + 2e^(-)
Zn^(2+) + 2Cl^(-) → Zn + Cl_2
∴ <em>n</em> = 2
<em>Step 2</em>. Calculate <em>K</em>
log<em>K</em> = <em>nE</em>°/0.0592 V = [2 × (-2.12 V)]/0.0592 V = -71.62
<em>K</em> = 10^(-71.62) = 2.4 × 10^(-72)
A free-radical substitution reaction is likely to be responsible for the observations. The reaction mechanism of a reaction like this can be grouped into three phases:
- Initiation; the "light" on the mixture deliver sufficient amount of energy such that the halogen molecules undergo homologous fission. It typically takes ultraviolet radiation to initiate fissions of the bonds.
- Propagation; free radicals react with molecules to produce new free radicals and molecules.
- Termination; two free radicals combine and form covalent bonds to produce stable molecules. Note that it is possible for two carbon-containing free-radicals to combine, leading to the production of trace amounts of long carbon chains in the product.
Initiation
where the big black dot indicates unpaired electrons attached to the atom.
Propagation
Termination
Answer:
Explanation:
- For the balanced reaction:
<em>4Fe(s) + 3O₂(g) → 2Fe₂O₃(s).</em>
It is clear that 4 mol of Fe react with 3 mol of O₂ to produce 2 mol of Fe₂O₃.
- Firstly, we need to calculate the no. of moles of 35.8 grams of Fe metal:
no. of moles of Fe = mass/molar mass = (35.8 g)/(55.845 g/mol) = 0.64 mol.
- Now, we can find the no. of moles of O₂ is needed to react with the proposed amount of Fe:
<em><u>Using cross multiplication:</u></em>
4 mol of Fe is needed to react with → 3 mol of O₂, from stichiometry.
0.64 mol of Fe is needed to react with → ??? mol of O₂.
∴ The no. of moles of O₂ needed = (3 mol)(0.64 mol)/(4 mol) = 0.48 mol.
- Finally, we can get the volume of oxygen using the information:
<em>It is known that 1 mole of any gas occupies 22.4 L at standard P and T (STP).</em>
<em></em>
<em><u>Using cross multiplication:</u></em>
1 mol of O₂ occupies → 22.4 L, at STP conditions.
0.48 mol of O₂ occupies → ??? L.
∴ The no. of liters of O₂ = (0.48 mol)(22.4 L)/(1 mol) = 10.752 L.
