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Mnenie [13.5K]
3 years ago
5

Calculate the standard cell potential given the following standard reduction potentials: Al3++3e−→Al;E∘=−1.66 V Cu2++2e−→Cu;E∘=0

.340 V
Chemistry
1 answer:
Maru [420]3 years ago
3 0

Answer:

Explanation:

To calculate the cell potential we use the relation:

Eº cell = Eº oxidation + Eº reduction

Now in order to determine which of the species is going to be oxidized, we have to remember that the more the value of the reduction potential is negative,  the greater its tendency to be oxidized is. In electrochemistry we use the values of the reductions potential in the tables for simplicity  because the only thing we need to do is change the sign of the reduction potential for the oxized species .

So the species that is going to be oxidized is the Aluminium, and therefore:

Eº cell = -( -1.66 V ) + 0.340 V =  5.06 V

Equally valid is to write the equation as:

Eº cell = Eº reduction for the reduced species - Eº reduction for the oxidized species

These two expressions are equivalent, choose the one you fell more comfortable but be careful with the signs.

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Consider a disubstituted aromatic compound. The parent name is benzene and there is a chloro and bromo substituent. Disubstitute
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Answer:The correct names for the structure are:

--> 1. 1-bromo-3-chlorobenzene.

--> 3. meta-bromochlorobenzene.

--> 6. m-bromochlorobenzene.

Explanation:

Benzene is the simplest member of the aromatic hydrocarbons. It has a ring structure consisting of six carbon and six hydrogen atoms. This equally means that a benzene can have up to six substituents. One of the chemical properties is that benzene and other members of its series undergo substitution reaction whereby one or more of its six hydrogen atoms is replaced by monoatomic reagents.

Disubstituted benzene consists of two substituents which are described based on either numerical locants or specific words for the three possible forms.

The numerical locant method are used the same naming substitutes of other hydrocarbons. From the question, the numerical locant method was derived through using the following steps:

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--> there are two substituents which includes bromine( written as bromo) and chlorine ( written as chloro)

--> while placing the number, it's done alphabetically ('1-bromo' comes before '3-chloro') in a clockwise manner. This is to give chorine the lowest locant number.

The second naming method for a disubstituted benzene is the the ortho-, meta-, para- (or their singel letter equivalent) nomenclature method. This is only used for benzene structures.

--> ortho or O : this is used when the substituents are close to each other in the benzene ring.

--> meta or (m) : This is used when the substituents are separated by one carbon in the benzene ring.

--> para or (p): This is used when the substituents are across each other in the benzene ring

From the question, the bromine substituent is separated from the chlorine by one carbon atom, therefore it's meta-bromochlorobenzene or m-bromochlorobenzene.

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Given :

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In simple words deshielding means the ability to shift protons .

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Therefore , deshielding will be more in CH_3Cl .

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