The normal rule to remember is 68-95-99.7, i.e. plus or minus three sigma corresponds to 99.7% of the probability. That leaves 0.3% in the two tails, or 0.15% in the tail above 3 sigma.
100% of the shelters received 1,000 or fewer cans per month since all the data values in the box and whisker plot are below 1,000 indicating that homeless shelter received more than 1,000 cans.