PLEASE HELP ME THIS IS TWENTY POINTS

Using the data, which of the following is the rate constant for the rearrangement of methyl isonitrile at 320 °C? (HINT: the act

algol13

Answer:

D) 2.3 x 10⁻¹ s⁻¹

Explanation:

The rate constant is related to the activation energy through the formula:

k= Ae^(-Eₐ /RT)

where A is the collision factor, Eₐ the activation energy, R is the gas constant ( 8.314 J/Kmol ) , and T is the temperature (K)

So a plot of lnk versus 1/T ( Arrehenius plot ) gives us a straight line with slope equal -Eₐ/R and intercept lnA

lnk = -(Eₐ/T)(1/T) + lnA

which has the form y= mx + b

In this problem, we can use the data provided to:

a) Using a calculator determine the slope and intercept and then calculate the value of rate constant at 320 ºC, or

b) Plot the data and determine the equation of the best line , and answer the question for k @ 320 ºC by reading the value from the plot.

Once you do the plot, the resulting equation is:

y = - 19 x 10³ x + 30,582 ( R² = 0.999 )

So for T = 320 + 273 K = 593 K

Y = 19 x 10³ X + 30.58

So for T = (320 + 273)K = 593 K

Y = -19 x 10³ ( 1/593) + 30.58 = -32.04 +30.58 = - 1.46

and then since

y = lnk ⇒ e^y = k

k= e^-1.46 = 2.3 x 10⁻¹ s⁻¹

Note: there is an error of transcription in the value for T = 472.1 ( 1/T = 2.118 x 10⁻³ and not 2.228 x 10⁻³). You can recognize this mistake if you plot the data and notice it produces an outlier.

5 0

4 years ago

A calorimeter contains 500 g of water at 25°C. You place a hand warmer containing 100 g of liquid sodium acetate (NaAC) inside t

antoniya [11.8K]

The heat absorbed by the water is
Q = 500 (4.18) (32.2 - 25)
Q = 15048 J

The enthalpy of fusion of the sodium acetate is:
ΔHf = Q / m
ΔHf = 15048 / 100
ΔHf = 150.48 J/g

3 0

3 years ago

Read 2 more answers

State which of the following set of quantum number would be possible and which would be permissible for an electron in an atom.

raketka [301]

Answer:

The correct option is: e) n=4, l=3, $m_{l}$ = - 2 , $m_{s}$ = - 1/2

Explanation:

The four quantum numbers that describe the electrons in an atom are: The principal: n, azimuthal: l, magnetic: m, and spin: s.

For a given electron, the values of the quantum numbers should be in the given range- principal quantum number: n ≥ 1;

azimuthal quantum number: 0 ≤ l ≤ n − 1;

magnetic quantum number: −l ≤ $m_{l}$ ≤ +l;

spin quantum number: −s ≤ $m_{s}$ ≤ +s

Now, for n= 4,

The value of l: 0 to n − 1 = 0 to 3 = 0, 1, 2, 3

The value of $m_{l}$ for l= 3 : -3 to +3 = -3, -2, -1, 0, +1, +2, +3

The value of $m_{s}$ : -1/2, +1/2

Therefore, the given set of quantum numbers: n=4, l=3, $m_{l}$ = - 2 , $m_{s}$ = - 1/2; are possible and permissible for an electron in an atom.

5 0

3 years ago

The volume of a fixed amount of gas is doubled, and the absolute temperature is doubled. According to the ideal gas law, how has

neonofarm [45]

Answer:

Option A. It has stayed the same.

Explanation:

To answer the question given above, we assumed:

Initial volume (V₁) = V

Initial temperature (T₁) = T

Initial pressure (P₁) = P

From the question given above, the following data were:

Final volume (V₂) = 2V

Final temperature (T₂) = 2T

Final pressure (P₂) =?

The final pressure of the gas can be obtained as follow:

P₁V₁/T₁ = P₂V₂/T₂

PV/T = P₂ × 2V / 2T

Cross multiply

P₂ × 2V × T = PV × 2T

Divide both side by 2V × T

P₂ = PV × 2T / 2V × T

P₂ = P

Thus, the final pressure is the same as the initial pressure.

Option A gives the correct answer to the question.

3 0

3 years ago

What is the basis for the classification of changes in matter into physical and chemical changes quizlet

laiz [17]

Explanation:

The basis for classifying changes in matter into physical and chemical change is to see if a material is altered after going through a process.

In a physical change only the state of matter is usually altered especially its form or shape.

Chemical change alters a substance by producing new kinds that are totally different from it.

In a chemical change, new kinds of matter are usually formed.
Such changes are usually irreversible.
Change of state is a reversible process.

learn more:

Chemical change brainly.com/question/9388643

#learnwithBrainly

6 0

3 years ago