<u>Answer:</u>
<u>For A:</u> The
for the given reaction is 
<u>For B:</u> The
for the given reaction is 1642.
<u>Explanation:</u>
The given chemical reaction follows:

The expression of
for the above reaction follows:

We are given:

Putting values in above equation, we get:

Hence, the
for the given reaction is 
Relation of
with
is given by the formula:

where,
= equilibrium constant in terms of partial pressure = 
= equilibrium constant in terms of concentration = ?
R = Gas constant = 
T = temperature = 500 K
= change in number of moles of gas particles = 
Putting values in above equation, we get:

Hence, the
for the given reaction is 1642.
I think it is B because you didn’t type the options
The easiest way is to use the Law of Gay-Lussac. This law states that there is a direct relation between the temperature in Kelvin of a gas and the pressure.
Then, namig p the pressure and T the temperature in Kelvin and using subscripts for every state:
p/T is constant ==> p_1 / T_1 = p_2/T_2
From which you obtain:
p_2 = [p_1 / T_1] * T_2
T_1 = 33.0 + 273.15 = 306.15 K
T _2 = 21.4 + 273.15 = 294.55 K
p_1 = 1014 kPa
p_2 = 1014 kPa * 294.55 K / 306.15 K = 975.6 kPa
We know 1 mole of any atom or molecules contains
atom or molecules.
1 mole of HBr i.e 81 gm/mol contains
atom or molecules.
So, mass of
molecules is :

Therefore, mass of
molecules is 1.21 gm .
Hence, this is the required solution.