A sample of potassium chlorate (15.0 g) is dissolved in 201 g of water at 70 °c with precautions taken to avoid evaporation of a
1 answer:
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Answer:
194.6 mL of SO₂
Explanation:
The reaction that takes place is:
P₄S₃ + 6O₂(g) → P₄O₁₀ + 3SO₂(g)
<u>To solve this problem we need to use PV=nRT</u>, so first let's convert the given units:
- 23.8 °C → 23.8 + 273.15 = 296.95 K
- 747 torr → 747/760 = 0.983 atm
We need to calculate V, so in order to do that we calculate n, using the mass of the reactant (P₄S₃):
0.576 g P₄S₃ * = 7.85 * 10⁻³ mol SO₂ = n
- Now we calculate V:
PV=nRT
0.983 atm * V = 7.85 * 10⁻³ mol * 0.082 atm·L·mol⁻¹·K⁻¹ * 296.95 K
V = 0.1946 L
- Finally we convert L into mL:
0.1946 * 1000 = 194.6 mL
Answer:
The structure with the ring flipped is the most stable
Explanation:
We have the trans 1,2 - dimethylcyclohexane. With the wedge/dash structure we could not figure is this form is stable (If we do a comparison with the cis structure). But when we do a chair structure and ring flipped structure, this is easier to look.
The picture attached shows the structures, they are labeled as 1, 2 and 3, according to this problem.
In the chair structure, according to the picture below, you can see that both methyls are heading in the axial positions of the ring (One facing upward and the other downward). This is pretty stable, however, when the methyls are in those positions, the methyl position 1, can undergoes an 1,3 diaxial interactions with the hydrogens atoms (They are not drawn, but still are there), so this interaction makes this structure a little less stable that it can be.
On the other side, the ring flipped structure, we can see that both methyls are in the equatorials positions of the ring, and in these positions, it can avoid the 1,4 diaxial interactions with the hydrogens atoms, making this structure the most stable structure.
Hope this helps
