Answer:
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Answer:
w = -531 kJ
1. Work was done by the system.
Explanation:
Step 1: Given data
- Heat gained by the system (q): 687 kJ (By convention, when the system absorbs heat, q > 0).
- Change in the internal energy of the system (ΔU°): 156 kJ
Step 2: Calculate the work done (w)
We will use the following expression.
ΔU° = q + w
w = ΔU° - q
w = 156 kJ - 687 kJ
w = -531 kJ
By convention, when w < 0, work is done by the system on the surroundings.
The empirical formula for pyrite is FeS2.
HOW TO CALCULATE EMPIRICAL FORMULA:
- The empirical formula represents the simplest whole number ratio of constituents element of a compound. The empirical formula of pyrite can be calculated as follows:
46.5 mass % Fe = 46.5g of Fe
53.5 mass % S = 53.5g of S
- Next, we divide each element's mass value by its molar mass
Fe = 46.5g ÷ 56g/mol = 0.83mol
S = 53.5g ÷ 32g/mol = 1.67mol
- Next, we divide each mole value by the smallest (0.83mol)
Fe = 0.83mol ÷ 0.83 = 1
S = 1.67mol ÷ 0.83 = 2.014
Approximately, the ratio of Fe to S is 1:2. Therefore, the empirical formula of pyrite is FeS2.
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Answer is: sulfuric acid is the limiting reactant.
Chemical reaction: 3H₂SO₄ + 2Al(OH)₃ → Al₂(SO₄)₃ + 6H₂O.
m(H₂SO₄) = 34 g.
n(H₂SO₄) = m(H₂SO₄) ÷ M(H₂SO₄).
n(H₂SO₄) = 34 g ÷ 98 g/mol.
n(H₂SO₄) = 0,346 mol.
m(Al(OH)₃) = 33 g.
n(Al(OH)₃) = 33 g ÷ 78 g/mol.
n(Al(OH)₃) = 0,423 mol.
From chemical reaction: n(H₂SO₄) : n(Al(OH)₃) = 3 : 2.
July 9, 1958: in Lituya Bay<span>, Alaska was caused by a landslide triggered by an 8.3 magnitude earthquake.</span>
