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Afina-wow [57]
2 years ago
13

W7L5 Stoichiometry Practice 2

Chemistry
1 answer:
Rzqust [24]2 years ago
6 0

Answer:

.079 moles of Nirogen gas (N2)

Explanation:

You can see from the equaton that each ONE mole of N2 produces TWO moles of NH3.

 Find the number of moles of NH3 produced.

    Using Periodic Table : Mole wt of NH3 = 17 gm/mole

          2.7 gm / 17 gm/mole = .1588 moles

      One half as many moles of N2 are needed  = .079 moles

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The molecule NH3 contains all single bonds.<br><br> true <br> false
dsp73
<h3><u>Answer;</u></h3>

True

<h3><u>Explanation</u>;</h3>
  • The molecule NH3 contains all single bonds.
  • NH3 has a three single covalent  bond among its nitrogen and hydrogen atoms,because one valence electron of each of three atom of hydrogen is shared with three electron.
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How can you determine which bond in a structure is more polar without using an electronegativity table?
UkoKoshka [18]
To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:

I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
3.0
EN
O
=
3.5
EN
F
=
4.0
EN
Cl
=
3.5
Notice how carbon through fluorine go in increments of
~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
0.4
Δ
EN
C
−
C
=
0.0
Δ
EN
C
−
O
=
1.0
Δ
EN
O
−
H
=
1.4
So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
C
−
Cl
≈
177 pm
r
C
−
C
≈
154 pm
r
C
−
O
≈
143 pm
r
C
−
F
≈
135 pm
r
C
−
H
≈
109 pm
r
O
−
H
≈
96 pm
So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
≈
70 pm
r
H
≈
53 pm
r
O
≈
60 pm
So assuming the answer is truly
C
−
C
, what would have to hold true is that:
The
C
−
F
bond polarization makes the carbon more electropositive (which is true).
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C
−
Cl
bond, and potentially the
C
−
H
bond (which is probably true).
The shortening of the
C
−
Cl
bond is somehow enough to be shorter than the
C
−
C
bond (this is debatable).
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