3-chloropropylamine what is?
1 answer:
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Answer:
Explanation:
One way to calculate the lattice energy is to use Hess's Law.
The lattice energy U is the energy released when the gaseous ions combine to form a solid ionic crystal:
Li⁺(g) + Cl⁻(g) ⟶ LiCl(s); U = ?
We must generate this reaction rom the equations given.
(1) Li(s) + ½Cl₂ (g) ⟶ LiCl(s); ΔHf° = -409 kJ·mol⁻¹
(2) Li(s) ⟶ Li(g); ΔHsub = 161 kJ·mol⁻¹
(3) Cl₂(g) ⟶ 2Cl(g) BE = 243 kJ·mol⁻¹
(4) Li(g) ⟶Li⁺(g) +e⁻ IE₁ = 520 kJ·mol⁻¹
(5) Cl(g) + e⁻ ⟶ Cl⁻(g) EA₁ = -349 kJ·mol⁻¹
Now, we put these equations together to get the lattice energy.
<u>E/kJ </u>
(5) Li⁺(g) +e⁻ ⟶ Li(g) 520
(6) Li(g) ⟶ Li(s) -161
(7) Li(s) + ½Cl₂(g) ⟶ LiCl(s) -409
(8) Cl(g) ⟶ ½Cl₂(g) -121.5
(9) Cl⁻(g) ⟶ Cl(g) + e⁻ <u>+349</u>
Li⁺(g) + Cl⁻(g) ⟶ LiCl(s) -862
The lattice energy of LiCl is .
Answer: Decreasing the temperature inside the container will decrease the pressure of a gas inside a closed cubical container.
Explanation:
According to Gay-Lussac's Law : 'The pressure of the gas increases with increase in temperature of the gas when volume of the gas is kept constant'.
At constant volume, pressure of the gas will decrease on decreasing the temperature or vice versa.
Decreasing the temperature inside the container will decrease the pressure of a gas inside a closed cubical container.