Answer:
Intermolecular forces (IMFs) can be used to predict relative boiling points. The stronger the IMFs, the lower the vapor pressure of the substance and the higher the boiling point. Therefore, we can compare the relative strengths of the IMFs of the compounds to predict their relative boiling points.
Explanation:
Let's eliminate these one by one.
The first pair would not be the same, as X would most likely be in group IA, and Y would be in group VIIA, because of their tendency to gain and lose electrons.
The second pair would also violate the same rule, but X would most likely be in group IIA, and Y would most likely be in group VIA.
The third pair would not be the same, as X is most likely in group VIIA, and since Y has eight valence electrons, it is most likely a noble gas.
The final pair has X with atomic number 15, making it phosphorous. Phosphorous wants to gain 3 electrons to have a full octet of 8 outer "valence" electrons, and Y would also like to gain 3 electrons. This means it is possible that the final pair would be in the same group.