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bagirrra123 [75]
2 years ago
9

How many grams of al(oh)3 (molar mass = 78.0 g/mol) can be produced from the reaction of 48.6 ml of .15 m koh with excess al2(so

4)3?
Chemistry
1 answer:
Fudgin [204]2 years ago
4 0

Taking into account the reaction stoichiometry, 0.18954 grams of Al(OH)₃ are formed from the reaction of 48.6 mL (0.0486 L) of 0.15 M KOH with excess Al₂(SO₄)₃.

<h3>Reaction stoichiometry</h3>

In first place, the balanced reaction is:

Al₂(SO₄)₃ + 6 KOH → 2 Al(OH)₃ + 3 K₂SO₄

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • Al₂(SO₄)₃: 1 mole
  • KOH: 6 moles
  • Al(OH)₃: 2 moles
  • K₂SO₄: 3 moles

The molar mass of the compounds is:

  • Al₂(SO₄)₃: 342 g/mole
  • KOH: 56.1 g/mole
  • Al(OH)₃: 78 g/mole
  • K₂SO₄: 174.2 g/mole

Then, by reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

  • Al₂(SO₄)₃: 1 mole ×342 g/mole= 342 grams
  • KOH: 6 moles ×56.1 g/mole= 336.6 grams
  • Al(OH)₃: 2 moles ×78 g/mole= 156 grams
  • K₂SO₄: 3 moles ×174.2 g/mole= 522.6 grams

<h3>Definition of molarity</h3>

Molarity is a measure of the concentration of a solute in a solution and indicates the number of moles of solute that are dissolved in a given volume:

Molarity= number of moles÷ volume

<h3>Mass of Al(OH)₃ formed</h3>

In firts place, you know that 48.6 mL (0.0486 L) of 0.15 M KOH react with excess Al₂(SO₄)₃.

Replacing in the definition, you can calculate the amount of moles of KOH that react:

0.15 M= number of moles÷ 0.0486 L

Solving:

0.15 M× 0.0486 L= number of moles

<u><em>0.00729 moles= number of moles</em></u>

Then, 0.00729 moles of KOH react with excess Al₂(SO₄)₃. So, following rule of three can be applied: if by reaction stoichiometry 6 moles of KOH form 156 grams of Al(OH)₃, 0.00729 moles of KOH form how much mass of Na₂SO₄?

mass of Al(OH)_{3} =\frac{0.00729 moles of KOHx156 grams of Al(OH)_{3}}{6 moles of KOH}

<u><em>mass of Al(OH)₃= 0.18954 grams</em></u>

Then, 0.18954 grams of Al(OH)₃ are formed from the reaction of 48.6 mL (0.0486 L) of 0.15 M KOH with excess Al₂(SO₄)₃.

Learn more about

the reaction stoichiometry:

brainly.com/question/24741074

brainly.com/question/24653699

molarity:

brainly.com/question/9324116

brainly.com/question/10608366

brainly.com/question/7429224

#SPJ1

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Answer:

1) The order of the reaction is of FIRST ORDER

2)   Rate constant k = 5.667 × 10 ⁻⁴

Explanation:

From the given information:

The composition of a liquid-phase reaction 2A - B was monitored spectrophotometrically.

liquid-phase reaction 2A - B signifies that the reaction is of FIRST ORDER where the rate of this reaction is directly proportional to the concentration of A.

The following data was obtained:

t/min                    0         10         20          30             40          ∞

conc B/(mol/L)    0       0.089    0.153     0.200       0.230    0.312

For  a first order reaction:

K = \dfrac{1}{t} \ In ( \dfrac{C_{\infty} - C_o}{C_{\infty} - C_t})

where :

K = proportionality  constant or the rate constant for the specific reaction rate

t = time of reaction

C_o = initial concentration at time t

C _{\infty} = final concentration at time t

C_t = concentration at time t

To start with the value of t when t = 10 mins

K_1 = \dfrac{1}{10} \ In ( \dfrac{0.312 - 0}{0.312 - 0.089})

K_1 = \dfrac{1}{10} \ In ( \dfrac{0.312 }{0.223})

K_1 =0.03358 \  min^{-1}

K_1 \simeq 0.034 \  min^{-1}

When t = 20

K_2= \dfrac{1}{20} \ In ( \dfrac{0.312 - 0}{0.312 - 0.153})

K_2= 0.05 \times  \ In ( 1.9623)

K_2=0.03371 \ min^{-1}

K_2 \simeq 0.034 \ min^{-1}

When t = 30

K_3= \dfrac{1}{30} \ In ( \dfrac{0.312 - 0}{0.312 - 0.200})

K_3= 0.0333 \times  \ In ( \dfrac{0.312}{0.112})

K_3= 0.0333 \times  \ 1.0245

K_3 = 0.03412 \ min^{-1}

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When t = 40

K_4= \dfrac{1}{40} \ In ( \dfrac{0.312 - 0}{0.312 - 0.230})

K_4=0.025 \times  \ In ( \dfrac{0.312}{0.082})

K_4=0.025 \times  \ In ( 3.8048)

K_4=0.03340 \ min^{-1}

We can see that at the different time rates, the rate constant of k_1, k_2, k_3, and k_4 all have similar constant values

As such :

Rate constant k = 0.034 min⁻¹

Converting it to seconds ; we have :

60 seconds = 1 min

∴

0.034 min⁻¹ =(0.034/60) seconds

= 5.667 × 10 ⁻⁴ seconds

Rate constant k = 5.667 × 10 ⁻⁴

4 0
3 years ago
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