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marishachu [46]
1 year ago
13

What is Racemic mixture?​

Chemistry
1 answer:
weqwewe [10]1 year ago
3 0

<u>Racemic </u><u>mixture</u>

An equimolar mixture of the enantiomers is called Racemic mixture. It may be represented as dl or (±)

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Find the atomicity of water.​
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One molecule of water contains two atoms of hydrogen and one atom of oxygen, the atomicity of water is three.
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True or False: If you have a covalent compound, the first element written in the formula will always be a nonmetal
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Phosgene, COCl2, gained notoriety as a chemical weapon in World War I. Phosgene is produced by the reaction of carbon monoxide w
jek_recluse [69]

The question is incomplete, here is the complete question:

Phosgene, COCl_2, gained notoriety as a chemical weapon in World War I. Phosgene is produced by the reaction of carbon monoxide with chlorine:  

CO(g)+Cl_2(g)\rightleftharpoons COCl_2(g)

The value of K_c for this reaction is 5.79 at 570 K. What are the equilibrium partial pressures of the three gases if a reaction vessel initially contains a mixture of the reactants in which p_{CO}=p_{Cl_2}=0.265atm and p_{COCl_2}=0.000atm ?

<u>Answer:</u> The equilibrium partial pressure of CO, Cl_2\text{ and }COCl_2 is 0.257 atm, 0.257 atm and 0.008 atm respectively.

<u>Explanation:</u>

The relation of K_c\text{ and }K_p is given by:

K_p=K_c(RT)^{\Delta n_g}

K_p = Equilibrium constant in terms of partial pressure

K_c = Equilibrium constant in terms of concentration = 5.79

\Delta n_g = Difference between gaseous moles on product side and reactant side = n_{g,p}-n_{g,r}=1-2=-1

R = Gas constant = 0.0821\text{ L. atm }mol^{-1}K^{-1}

T = Temperature = 570 K

Putting values in above equation, we get:

K_p=5.79\times (0.0821\times 570)^{-1}\\\\K_p=0.124

We are given:

Initial partial pressure of CO = 0.265 atm

Initial partial pressure of chlorine gas = 0.265 atm

Initial partial pressure of phosgene = 0.00 atm

The given chemical equation follows:

                      CO(g)+Cl_2(g)\rightleftharpoons COCl_2(g)

<u>Initial:</u>            0.265      0.265

<u>At eqllm:</u>        0.265-x    0.265-x        x

The expression of K_p for above equation follows:

K_p=\frac{p_{COCl_2}}{p_{CO}\times p_{Cl_2}}

Putting values in above equation, we get:

0.124=\frac{x}{(0.265-x)\times (0.265-x)}\\\\x=0.0082,8.59

Neglecting the value of x = 8.59 because equilibrium partial pressure cannot be greater than initial pressure

So, the equilibrium partial pressure of CO = (0.265-x)=(0.265-0.008)=0.257atm

The equilibrium partial pressure of Cl_2=(0.265-x)=(0.265-0.008)=0.257atm

The equilibrium partial pressure of COCl_2=x=0.008atm

Hence, the equilibrium partial pressure of CO, Cl_2\text{ and }COCl_2 is 0.257 atm, 0.257 atm and 0.008 atm respectively.

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4. Arrange the following substances in order of increasing boiling point: CH3CH2OH, HOCH2CH2OH, CH3CH2Cl , and ClCH2CH2OH A. CH3
Studentka2010 [4]

Answer: Option (B) is the correct answer.

Explanation:

A molecules that will have more number of hydrogen bonding will has highest boiling point because to break the hydrogen bonds high heat needs to be provided.

So, in the molecule HOCH_{2}CH_{2}OH there is presence of two alcoholic groups. Hence, it will have strongest hydrogen bonding as compared to the rest of molecules.

In the molecule ClCH_{2}CH_{2}OH there will be hydrogen bonding and dipole-dipole interactions. Hence, it boiling point will be slightly less than HOCH_{2}CH_{2}OH.

In the molecule CH_{3}CH_{2}OH, there will be only hydrogen bonding. Hence, its boiling point is less than ClCH_{2}CH_{2}OH.

In the molecule CH_{3}CH_{2}Cl, there is no hydrogen bonding but there will be only dipole-dipole interactions. Hence, its boiling point will be the least.

Therefore, we can conclude that increasing order of boiling point will be as follows.

        CH_{3}CH_{2}Cl < CH_{3}CH_{2}OH < ClCH_{2}CH_{2}OH < HOCH_{2}CH_{2}OH

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