The concentration of solids is constant and usually taken equal to unity ,therefore it does not appear in the equilibrium constant ,so adding or removing solid has no effect. So According to Le Chatelet's Principle the amount of solid reactant or product present does not have an impact on the equilibrium
What is Le Chatelet's Principle ?
The position of the equilibrium in a chemical reaction can be predicted with the aid of Le Chatelet's Principle in response to changes in temperature, concentration, or pressure. This is crucial, especially for industrial applications where it's crucial to predict and maximize yields.
According to Le Châtelet's principle, if a dynamic equilibrium is upset by changing the conditions, the equilibrium position will move to compensate for the change and restore the equilibrium.
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