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riadik2000 [5.3K]
3 years ago
7

luminum and oxygen react according to the following equation: 4Al(s) +3O2(g) --> 2Al2O3(s) What mass of Al2O3, in grams, can

be made by reacting 4.6 g Al with excess oxygen?
Chemistry
1 answer:
Slav-nsk [51]3 years ago
8 0

Answer: 8.7 grams

Explanation:

According to avogadro's law, 1 mole of every substance occupies 22.4 L at STP and contains avogadro's number 6.023\times 10^{23} of particles.  

To calculate the moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text {Molar mass}}=\frac{4.6g}{27g/mol}=0.17moles

4Al(s)+3O_2(g)\rightarrow 2Al_2O_3(s)

As oxygen is in excess, Aluminium is the limiting reagent and limits the formation of products.

According to stoichiometry:

4 moles of aluminium give = 2 moles of Al_2O_3(s)

Thus 0.17 moles of aluminium give=\frac{2}{4}\times 0.17=0.085mol

Mass of Al_2O_3=moles\times {\text {molar mass}}=0.085\times 102g/mol=8.7g

Thus the mass of Al_2O_3(s)  is 8.7 grams

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⇒ MnO₄⁻ + 5e⁻ + 8H⁺ → Mn²⁺ + 4H₂O               .....equation 1

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⇒ SO₃²⁻ → SO₄²⁻ + 2e⁻ + 2H⁺

To balance the number of hydrogen and oxygen atoms, 1 H₂O must be added to the reactant side.

⇒ SO₃²⁻ + H₂O → SO₄²⁻ + 2e⁻ + 2H⁺                .....equation 2

<u>Now, to cancel the electrons transferred, equation (1) is multiplied by 2 and equation (2) is multiplied by 5.</u>

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⇒ 2MnO₄⁻ + 10e⁻ + 16H⁺ → 2Mn²⁺ + 8H₂O                .....equation 3

<u>Balanced Oxidation half-reaction:</u>

SO₃²⁻ + H₂O → SO₄²⁻ + 2e⁻ + 2H⁺ ] × 5

⇒ 5SO₃²⁻ + 5H₂O → 5SO₄²⁻ + 10e⁻ + 10H⁺                  .....equation 4  

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2MnO₄⁻ + 5SO₃²⁻ + 6H⁺ → 2Mn²⁺ + 5SO₄²⁻ + 3H₂O

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