The number of moles of gas lost is 0.0213 mol. It can be solved with the help of Ideal gas law.
<h3>What is Ideal law ?</h3>
According to this law, "the volume of a given amount of gas is directly proportional to the number on moles of gas, directly proportional to the temperature and inversely proportional to the pressure. i.e.
PV = nRT.
Where,
- p = pressure
- V = volume (1.75 L = 1.75 x 10⁻³ m³)
- T = absolute temperature
- n = number of moles
- R = gas constant, 8.314 J*(mol-K)
Therefore, the number of moles is
n = PV / RT
State 1 :
- T₁ = (25⁰ C = 25+273 = 298 K)
- p₁ = 225 kPa = 225 x 10³ N/m²
State 2 :
- T₂ = 10 C = 283 K
- p₂ = 185 kPa = 185 x 10³ N/m²
The loss in moles of gas from state 1 to state 2 is
Δn = V/R (P₁/T₁ - P₂/T₂ )
V/R = (1.75 x 10⁻³ m³)/(8.314 (N-m)/(mol-K) = 2.1049 x 10⁻⁴ (mol-m²-K)/N
p₁/T₁ = (225 x 10³)/298 = 755.0336 N/(m²-K)
p₂/T₂ = (185 x 10³)/283 = 653.7102 N/(m²-K)
Therefore,
Δn = (2.1049 x 10⁻⁴ (mol-m²-K)/N)*(755.0336 - 653.7102 N/(m²-K))
= 0.0213 mol
Hence, The number of moles of gas lost is 0.0213 mol.
Learn more about ideal gas here ;
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<u>Answer:</u> The
for the reaction is 54.6 kJ/mol
<u>Explanation:</u>
For the given balanced chemical equation:

We are given:

- To calculate
for the reaction, we use the equation:
![\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G_f%28product%29%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G_f%28reactant%29%5D)
For the given equation:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28COCl_2%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28CO_2%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28CCl_4%29%7D%29%5D)
Putting values in above equation, we get:
![\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%28-204.9%29%29-%28%281%5Ctimes%20%28-394.4%29%29%2B%281%5Ctimes%20%28-62.3%29%29%29%5D%5C%5C%5CDelta%20G%5Eo_%7Brxn%7D%3D46.9kJ%3D46900J)
Conversion factor used = 1 kJ = 1000 J
- The expression of
for the given reaction:

We are given:

Putting values in above equation, we get:

- To calculate the Gibbs free energy of the reaction, we use the equation:

where,
= Gibbs' free energy of the reaction = ?
= Standard gibbs' free energy change of the reaction = 46900 J
R = Gas constant = 
T = Temperature = ![25^oC=[25+273]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B25%2B273%5DK%3D298K)
= equilibrium constant in terms of partial pressure = 22.92
Putting values in above equation, we get:

Hence, the
for the reaction is 54.6 kJ/mol
There are 3 ways,
1) Increase the temperature of the solvent- The higher the temperature of the solvent, the faster we can expect the solute to dissolve
2 )Increase the rate of stirring- The faster the rate at which we stir the mixture, the faster we can expect the solute to dissolve
3) Decrease the size of the solute particles- The smaller the size of the particles, the faster we can expect the solute to dissolve in the. This is because small particles have a larger surface area that come into contact with the solvent
Hope this helps :)
Let's write the balanced chemical reaction for this:
K₂CrO₄ + Pb(CH₃COO)₂ --> PbCrO₄ + 2 CH₃COOK
The products are lead(ii) chromate and potassium acetate. As you can notice, there is an exchange of ions involved for both reactants. This type ofreaction is called the <em>double-replacement reaction or also called metathesis</em>.