gypsum is hydrated calcium sulfate. a 4.89 g sample of this hydrate was heated, and after the water was driven off, 3.87 g anhyd
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The amount of Al required will be 15.77 grams
<h3>Stoichiometric problem</h3>First, the equation of the reaction:
The mole ratio is 2:3.
Mole of 63.0 g of FeO = 63/71.84 = 0.8769 moles
Equivalent moles of Al = 0.8769 x 2/3 = 0.5846 moles
Mass of 0.5846 moles Al = 0.5846 x 26.98 = 15.77 grams
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Those Hydrogen atoms which are present at alpha position to carbonyl group are mildly acidic in nature. When such acidic proton containing carbonyl compounds are treated with strong base, they yield enolates. The negative charge created on alpha carbon resonates and shifts to carbonyl oxygen resulting in formation of carbon double bond carbon.
In <span>tert−butyl methyl ketone there are two carbons at each alpha position. Among these two carbons only methyl carbon contains hydrogen atoms while the second one is bonded to further three carbons making it Quaternary carbon. The base abstracts proton from methyl group and enolate is formed.
</span>tert−butyl methyl ketone in this case acts as acid, Hydroxyl ion acts as base, while the enolate generated is the conjugate base of <span>tert−butyl methyl ketone and Water produced is the conjugate acid of hydroxide ion.</span>
In <span>tert−butyl methyl ketone there are two carbons at each alpha position. Among these two carbons only methyl carbon contains hydrogen atoms while the second one is bonded to further three carbons making it Quaternary carbon. The base abstracts proton from methyl group and enolate is formed.
</span>tert−butyl methyl ketone in this case acts as acid, Hydroxyl ion acts as base, while the enolate generated is the conjugate base of <span>tert−butyl methyl ketone and Water produced is the conjugate acid of hydroxide ion.</span>