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Alex_Xolod [135]
3 years ago
14

When 2 crystalline solid barium hydroxide octahydrate and crystalline solid ammonium nitrate are mixed in a beaker at room tempe

rature, a spontaneous reaction occurs. the temperature of the beaker contents rapidly falls to below 0º
c. use this information to decide whether the reaction is exothermic or endothermic and what the signs of δh and δs are?
Chemistry
1 answer:
podryga [215]3 years ago
5 0
It is endothermic reaction ΔH>0 (sign is +).
Because it is spontaneous reaction ΔG<span><0 (Gibbs free energy)
</span>ΔG=ΔH-TΔS, so must be TΔS>ΔH and ΔS<span>>0 (sign +).</span>
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Hi!


The correct option would be A.


This is because the displacement reaction would take place as follows

Ca + ZnCl2 --> CaCl2 + Zn


A displacement reaction is one in which a substitution occurs, as the more reactive element in the mixture replaces one that is less reactive.

In the electrochemical series, we find Ca higher than Zn, which is indicative of Ca being more reactive, and having the capacity to displace Zn to form a compound.


Option D would be incorrect as no such substitution occurs.

Option B would be incorrect because again, there is no substitution occurring, and also because two metals alone (Ca and Zn in our case) can never react to form a compound.

Option C would be incorrect because it is not possible because CaCl and ZnCl are forms that are too unstable to exist due to an overall positive charge.


Hope this helps!

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