Answer:
E°(Ag⁺/Fe°) = 0.836 volt
Explanation:
3Ag⁺ + 3e⁻ => Ag°; E° = +0.800 volt
Fe° => Fe⁺³ + 3e⁻ ; E° = -0.036 volt
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Fe°(s) + 3Ag⁺(aq) => Fe⁺³(aq) + 3Ag°(s) ...
E°(Ag⁺/Fe°) = E°(Ag⁺) - E°(Fe°) = 0.800v - ( -0.036v) = 0.836 volt
When we can get Pka for K2HPO4 =6.86 so we can determine the Ka :
when Pka = - ㏒ Ka
6.86 = -㏒ Ka
∴Ka = 1.38 x 10^-7
by using ICE table:
H2PO4- → H+ + HPO4
initial 0.4 m 0 0
change -X +X +X
Equ (0.4-X) X X
when Ka = [H+][HPO4] / [H2PO4-]
by substitution:
1.38 X 10^-7 = X^2 / (0.4-X) by solving for X
∴X = 2.3x 10^-4
∴[H+] = X = 2.3 x 10^-4
∴PH = -㏒[H+]
= -㏒ (2.3 x 10^-4)
∴PH = 3.6
Answer:
2.7 °C.kg/mol
Explanation:
Step 1: Calculate the freezing point depression (ΔT)
The normal freezing point of a certain liquid X is-7.30°C and the solution freezes at -9.9°C instead. The freezing point depression is:
ΔT = -7.30 °C - (-9.9 °C) = 2.6 °C
Step 2: Calculate the molality of the solution (b)
We will use the following expression.
b = mass of solute / molar mass of solute × kilograms of solvent
b = 102. g / (162.2 g/mol) × 0.650 kg = 0.967 mol/kg
Step 3: Calculate the molal freezing point depression constant Kf of X
Freezing point depression is a colligative property. It can be calculated using the following expression.
ΔT = Kf × b
Kf = ΔT / b
Kf = 2.6 °C / (0.967 mol/kg) = 2.7 °C.kg/mol
