I would say #3 I’m sorry if it’s wrong tho
Missing in your question Ka2 =6.3x10^-8
From this reaction:
H2SO3 + H2O ↔ H3O+ + HSO3-
by using the ICE table :
H2SO3 ↔ H3O + HSO3-
intial 0.6 0 0
change -X +X +X
Equ (0.6-X) X X
when Ka1 = [H3O+][HSO3-]/[H2SO3]
So by substitution:
1.5X10^-2 = (X*X) / (0.6-X) by solving this equation for X
∴ X = 0.088
∴[H2SO3] = 0.6 - 0.088 = 0.512
[HSO3-] = [H3O+] = 0.088
by using the ICE table 2:
HSO3- ↔ H3O + SO3-
initial 0.088 0.088 0
change -X +X +X
Equ (0.088-X) (0.088+X) X
Ka2= [H3O+] [SO3-] / [HSO3-]
we can assume [HSO3-] = 0.088 as the value of Ka2 is very small
6.3x10^-8 = (0.088+X)*X / 0.088
X^2 +0.088 X - 5.5x10^-9= 0 by solving this equation for X
∴X= 6.3x10^-8
∴[H3O+] = 0.088 + 6.3x10^-8
= 0.088 m ( because X is so small)
∴PH= -㏒[H3O+]
= -㏒ 0.088 = 1.06
Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp =
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104![[P(NO_{2} )]^{2}](https://tex.z-dn.net/?f=%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D)
+ 
- 200 = 0
Resolving the second degree equation:
= 
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are = 98.7 MPa and P(N₂O₄) = 101.3 MPa
Answer:
when CO2 gas is passed through lime water it turns milky due to the formation of calcium carbonate which formula is CaCO3.
Ca(OH)2+ CO2------ CaCO3
when excess of carbon dioxide is passed through calcium carbonate calcium hydrogen carbonate is formed and solution become colourless.
CaCO3+CO2------ Ca(HCO3)
Molar mass of 13c = 13 grams
number of moles = mass / molar mass
therefore,
number of moles = 7 / 13
To know the number of atoms in 7/13 moles, we simply multiply the number of moles by Avogadro's number as follows:
number of atoms = (7/13) x 6.022 x 10^23 = 3.2426 x 10^23 atoms
