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scoundrel [369]
2 years ago
6

A student needs to prepare 50.0 mL of a 1.20 M aqueous H2O2 solution. Calculate the volume of 4.9 M H2O2 stock solution that sho

uld be used to prepare the solution.
Chemistry
1 answer:
Nonamiya [84]2 years ago
3 0

Answer : The volume of 4.9 M H_2O_2 stock solution used to prepare the solution is, 12.24 ml

Solution : Given,

Molarity of aqueous H_2O_2 solution = 1.20 M = 1.20 mole/L

Volume of aqueous H_2O_2 solution = 50.0 ml = 0.05 L

(1 L = 1000 ml)

Molarity of H_2O_2 stock solution = 4.9 M = 4.9 mole/L

Formula used :

M_1V_1=M_2V_2

where,

M_1 = Molarity of aqueous H_2O_2 solution

M_2 = Molarity of H_2O_2 stock solution

V_1 = Volume of aqueous H_2O_2 solution

V_2 = Volume of H_2O_2 stock solution

Now put all the given values in this formula, we get the volume of H_2O_2 stock solution.

(1.20mole/L)\times (0.05L)=(4.9mole/L)\times V_2

By rearranging the term, we get

V_2=0.01224L=12.24ml

Therefore, the volume of 4.9 M H_2O_2 stock solution used to prepare the solution is, 12.24 ml

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(a) One form of the Clausius-Clapeyron equation is

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Solving for ΔHv:

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(b) <em>Normal boiling point means</em> that P = 1 atm = 101.325 kPa. We use the same formula, using the same values for P₁ and T₁, and replacing P₂ with atmosferic pressure, <u>solving for T₂</u>:

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  • 1/T₂ = 1/T₁ - [ ln(P₂/P₁) / (ΔHv/R) ]
  • 1/T₂ = 1/358.96 K - [ ln(101.325/1.3) / (49111.12/8.31) ]
  • 1/T₂ = 2.049 * 10⁻³ K⁻¹
  • T₂ = 488.1 K = 214.94 °C

(c)<em> The enthalpy of vaporization</em> was calculated in part (a), and it does not vary depending on temperature, meaning <u>that at the boiling point the enthalpy of vaporization ΔHv is still 49111.12 J/molK</u>.

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