Each Be–Cl bond is polar because the two atoms have different electronegativities. The number of outer atoms (2) and lone pairs on the central atom (0) indicate that this molecule has a linear geometry. The bonds in a linear molecule are symmetric, and so their dipoles cancel out.
Each O–H bond is polar because the two atoms have different electronegativities. The number of outer atoms (2) and lone pairs on the central atom (2) indicate that this molecule has a bent geometry. The bonds in a bent molecule are asymmetric, and so their dipoles do not cancel out. In addition, the asymmetric arrangement of the lone pairs on O further contribute to the dipole of this molecule.
An O–O or O=O bond is nonpolar because the two atoms have the same electronegativity. Because there is no overall polarity in O2, the molecule is nonpolar.
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Answer:
an increase in 1-butene was observed when t-butoxide was used
Explanation:
When a base reacts with an alkyl halide, an elimination product is formed. This reaction is an E2 reaction.
Here we are to compare the reaction of two different bases with one substrate; 2-bromobutane. Both reactions occur by the E2 mechanism but follow different transition states due to the size of the base.
The Saytzeff product, 2-butene, is obtained when the methoxide is used while the non Saytzeff product, 1-butene, is obtained when t-butoxide is used.
The Saytzeff rule is reliable in predicting the major products of simple elimination reactions of alkyl halides given the fact that a small/strong bases is used for the elimination reaction. Therefore hydroxide, methoxide and ethoxide bases give similar results for the same alkyl halide substrate. Bulky bases such as tert-butoxide tend to yield a higher percentage of the non Saytzeff product and this is usually attributed to steric hindrance.
20. Would be the right answer
