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Naddik [55]
3 years ago
12

ViT2 = V2T, V = V2

Chemistry
1 answer:
shusha [124]3 years ago
7 0

Answer:

V₂ = 285 mL

Explanation:

Given data:

Initial volume of bag = 250 mL

Initial temperature = 19.0°C

Final temperature = 60.0°C

Final volume = ?

Solution:

The given problem will be solved by using Charles Law,

This law stated that " The volume of given amount of gas at constant pressure and constant number of moles is directly proportional to its temperature"

Mathematical relationship:

V₁/T₁  = V₂/T₂

Now we will convert the temperature into kelvin.

Initial temperature = 19.0 + 273 = 292K

Final temperature = 60.0 + 273 = 333K

Now we will put the values in formula:

V₁/T₁  = V₂/T₂

250 mL / 292K  =  V₂/ 333K

0.856 mL /K = V₂/ 333K

V₂ = 0.86×333K. mL /K

V₂ = 285 mL

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Calculate the unit cell edge length for an 85 wt% fe-15 wt% v alloy. All of the vanadium is in solid solution, and, at room temp
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Answer is 0.289nm.

Explanation: The wt % of Fe and wt % of V is given for a Fe-V alloy.

wt % of Fe in Fe-V alloy = 85%

wt % of V in Fe-V alloy = 15%

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For calculating edge length,

a=(\frac{Z\times M_{ave}}{\rho_{ave}\times N_A})^{1/3}

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Similarly for calculating (\rho)_{ave}, we use the formula

\rho_{ave}= \frac{100}{\frac{(wt\%)_{Fe}}{\rho_{Fe}}+\frac{(wt\%)_{V}}{\rho_V}}

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Putting  M_{ave} and \rho_{ave} formula's in edge length formula, we get

a=\left [\frac{Z\left (\frac{100}{\frac{(wt\%)_{Fe}}{M_{Fe}}+\frac{(wt\%)_{Fe}}{M_{Fe}}}  \right )}{N_A\left (\frac{100}{\frac{(wt\%)_V}{\rho_V}+\frac{(wt\%)_V}{\rho_V}}  \right )}  \right ]^{1/3}

a=\left [\frac{2atoms/\text{unit cell}\left (\frac{100}{\frac{85\%}{55.85g/mol}+\frac{15\%}{50.941g/mol}}  \right )}{(6.023\times10^{23}atoms/mol)\left (\frac{100}{\frac{85\%}{7.874g/cm^3}+\frac{15\%}{6.10g/cm^3}}  \right )}  \right ]^{1/3}

By calculating, we get

a=2.89\times10^{-8}cm=0.289nm

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